Hexamethyldisiloxane (HMDSO)-plasma-polymerised coatings as primer for iron corrosion protection: influence of RF bias

Vautrin-Ul, Christine; Roux, F.; Boisse‐Laporte, C.; Louis, Pastol, Jean; Chaussé, A.

doi:10.1039/b111509j

Cited by 60 publications

(48 citation statements)

References 32 publications

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“…HMDSO coatings applied by plasma polymerization adhere well to most materials and have previously been used as barrier coatings to protect iron from corrosion in NaCl solution [25,26].…”

Section: Introductionmentioning

confidence: 99%

Long-term corrosion protection by a thin nano-composite coating

Ejenstam

Tuominen²,

Haapanen

et al. 2015

Applied Surface Science

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“…HMDSO coatings applied by plasma polymerization adhere well to most materials and have previously been used as barrier coatings to protect iron from corrosion in NaCl solution [25,26].…”

Section: Introductionmentioning

confidence: 99%

Long-term corrosion protection by a thin nano-composite coating

Ejenstam

Tuominen²,

Haapanen

et al. 2015

Applied Surface Science

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“…First plasma polymer coatings were deposited using the siliconorganic monomer hexamethylsiloxane (HMDSO). It is known from RF-and microwave plasma experiments that plasmapolymers deposited in a HMDSO-oxygen plasma can be varied from a soft, silicone-like structure to a hard, amorphous silicon oxide [1,2]. The ability of the VHF plasma process to deposit HMDSO plasma polymers with high rates and different structure was characterized using deposition rates as a function of flow and VHF-power.…”

Section: Introductionmentioning

confidence: 99%

Large area deposition of functional plasma polymers on polymer substrates

2006

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In this work we present a new plasma deposition apparatus developed for the effective plasma polymer deposition on polymeric substrates. It consists of a specially designed plasma reactor with a 60 MHz capacitively coupled electrode and an adapted substrate holder to implement roll-to-roll processes. Using siliconorganic precursors the high deposition rates required for industrial scale deposition on plastic films are achieved. The deposition mechanism is characterized by deposition rate as a function of power and monomer flow. Infrared spectroscopy investigation of the deposited thin films confirm the ability to include functional groups in siliconorganic and pure hydrocarbon plasma polymers in the 60 MHz plasma.PACS : 81.15.Gh

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“…However, the band is smaller than the Si-O-Si one. Indeed, the dissociation of TMDS starts rather by the loss of methyl functions as the binding energy between silicon and carbon is smaller than that between silicon and oxygen [3,17]. The contribution of Si-H stretching bands observed at ≈ 2,090 cm -1 is rather weak.…”

Section: Ftir and Raman Characterisationmentioning

confidence: 99%

Anticorrosion behaviour of amorphous silicon-based coatings prepared by remote cold plasma-assisted chemical vapour deposition process

Delimi

2018

GJPAAS

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Organosilicon films were deposited on carbon steel samples using remote microwave nitrogen plasma-assisted chemical vapour deposition. The deposits were obtained using TetraMethyDisoloxane monomer mixed with oxygen. The formed films were characterised using electron microprobe analysis, Fourier transformed infrared spectroscopy, contact angle measurements, scanning electron microscopy and atomic force microscopy. The electrochemical properties of the organosilicon coatings were evaluated using gravimetric experiments next to electrochemical tests. A significant increase in the corrosion resistance behaviour of the organosilicon coated carbon steel specimen was found when the samples were immersed in 3% aqueous sodium chloride solutions. Also, the surface pre-treatment process of carbon steel had an important influence on the morphological and electrochemical behaviour. Argon pre-treatment improves significantly the corrosion resistance or organosilicon coated steel samples. Gravimetric tests in particular showed that samples pre-treated with argon result in lower weight loss and decreased corrosion rates compared to interfaces pre-treated with nitrogen plasma.

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Hexamethyldisiloxane (HMDSO)-plasma-polymerised coatings as primer for iron corrosion protection: influence of RF bias

Cited by 60 publications

References 32 publications

Long-term corrosion protection by a thin nano-composite coating

Long-term corrosion protection by a thin nano-composite coating

Large area deposition of functional plasma polymers on polymer substrates

Anticorrosion behaviour of amorphous silicon-based coatings prepared by remote cold plasma-assisted chemical vapour deposition process

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