“…It is not possible to get a perfect fit from the scattered plot, therefore the values obtained on the first day were only estimates. The scattering of EIS data of the hydrophobic coating was also observed in other studies [18,27] and this is likely due to the presence of air bubbles on the coating/electrolyte interface due to the super-hydrophobic surface. During measurement, the bubbles could collapse and be diffused out of the system, causing agitation and system instability.…”
Section: Eis Analysis Of the Coating Systemsupporting
confidence: 80%
“…Lina Ejenstam et al [18] investigated the corrosion properties of hydrophobic multilayer nano-composite coating using a thin composite polyester acrylate (PEA)-TiO 2 -hexamethyl disiloxane (HMDSO) coating system. The study shows that it required all three layers to reach and maintain the desired corrosion protective property.…”
Understanding the corrosion inhibition behavior of super-amphiphobic coating is important to ensure practicability in the real application. 2 layers system of super-amphiphobic coating was successfully developed using functionalized nano-Al 2 O 3 incorporated in polyvinylidene fluoride (PVDF). This study investigates the effect of different amount of functionalizing agent on the coating's repellency and its relationship toward the corrosion inhibition behavior. We found that a higher amount of fluoroalkylsilane (FAS) led to a decreased in repellency of both water and oil. Electrochemical impedance spectroscopy (EIS) analysis suggests that the synergetic effect between super-hydrophobicity, longer diffusion path, and barrier effect; enhanced the corrosion resistance. Although the coatings demonstrate similar behavior, the most superhydrophobic/amphiphobic coating C1 offers the highest corrosion protection.
“…It is not possible to get a perfect fit from the scattered plot, therefore the values obtained on the first day were only estimates. The scattering of EIS data of the hydrophobic coating was also observed in other studies [18,27] and this is likely due to the presence of air bubbles on the coating/electrolyte interface due to the super-hydrophobic surface. During measurement, the bubbles could collapse and be diffused out of the system, causing agitation and system instability.…”
Section: Eis Analysis Of the Coating Systemsupporting
confidence: 80%
“…Lina Ejenstam et al [18] investigated the corrosion properties of hydrophobic multilayer nano-composite coating using a thin composite polyester acrylate (PEA)-TiO 2 -hexamethyl disiloxane (HMDSO) coating system. The study shows that it required all three layers to reach and maintain the desired corrosion protective property.…”
Understanding the corrosion inhibition behavior of super-amphiphobic coating is important to ensure practicability in the real application. 2 layers system of super-amphiphobic coating was successfully developed using functionalized nano-Al 2 O 3 incorporated in polyvinylidene fluoride (PVDF). This study investigates the effect of different amount of functionalizing agent on the coating's repellency and its relationship toward the corrosion inhibition behavior. We found that a higher amount of fluoroalkylsilane (FAS) led to a decreased in repellency of both water and oil. Electrochemical impedance spectroscopy (EIS) analysis suggests that the synergetic effect between super-hydrophobicity, longer diffusion path, and barrier effect; enhanced the corrosion resistance. Although the coatings demonstrate similar behavior, the most superhydrophobic/amphiphobic coating C1 offers the highest corrosion protection.
“…Also, hydrophobisation of the surface of wood materials is an important field (Moghaddam et al, 2013;Moghaddam et al, 2014), where direct nanoparticle deposition from the LFS has also been applied successfully (Moghaddam et al, 2015;Moghaddam et al, 2016). Superhydrophobic coatings can also be used to affect the corrosion properties of the surface (Ejenstam et al, 2013;Ejenstam et al, 2015a;Ejenstam et al, 2016), with a potential application field also for nanoparticle coatings (Ejenstam et al, 2015b). nanoparticle deposit on a paperboard (see e.g.…”
In this review article, a specific flame spray pyrolysis method, Liquid Flame Spray (LFS), is introduced to produce nanoparticles using a coflow type hydrogen-oxygen flame utilizing pneumatically sprayed liquid precursor. This method has been widely used in several applications due to its characteristic features, from producing nanopowders and nanostructured functional coatings to colouring of art glass and generating test aerosols. These special characteristics will be described via the example applications where the LFS has been applied in the past 20 years.
“…27 This improvement in the corrosion resistance of WBPU coating in the presence of DP nano-particles is attributed to; DP nanoparticles are well dispersed in WBPU coating, which restrict the diffusion of the corrosive ions and water through the WBPU coating lm. 28,29 Moreover, the large surface area and the small size of DP nano-particles, absorb more WBPU coating on its surface which reinforces the density of the WBPU coating lms, that way the transport paths for the corrosive ions and water to pass through the WBPU coating become longer and consequently inhibiting the corrosion process. 30 The effect of long time immersion of WBPU + 1.0% DP coating was shown in Fig.…”
Here we investigate the influence of new acidic pyrophosphate (Rb2Co(H2P2O7)2·2H2O) (DP) incorporation in waterborne polyurethane (WBPU) coatings on the corrosion protection efficiency of WBPU coatings for carbon steel in 3.5% NaCl solution.
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