Front Cover: Chemoselective C–S/S–S Formation between Diaryl Disulfides and Tetraalkylthiuram Disulfides (Eur. J. Org. Chem. 47/2019)

Abstract

The Front Cover shows an efficient C–S/S–S formation for the chemo‐selective synthesis of aryl dithio‐carbamates and aryl dialkylcarbamo‐(dithioperoxo)thioates. The approach uses inexpensive and readily available diphenyl disulfides and tetramethyl thiuram disulfides as starting materials, a series of aryl dithiocarbamates and aryl dimethylcarbamo(dithioperoxo)thioates could be furnished smoothly in moderate to good yields by modulating the reaction temperature, base, and catalyst. The S–S bond formation was confirmed by X‐ray crystallography. More information can be found in the Full Paper by Z.‐B. Dong et al.

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