2018
DOI: 10.1021/acsnano.8b05628
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Electronic Properties of Transferable Atomically Thin MoSe2/h-BN Heterostructures Grown on Rh(111)

Abstract: Vertically stacked two-dimensional (2D) heterostructures composed of 2D semiconductors have attracted great attention. Most of these include hexagonal boron nitride (h-BN) as either a substrate, an encapsulant, or a tunnel barrier. However, reliable synthesis of large-area and epitaxial 2D heterostructures incorporating BN remains challenging. Here, we demonstrate the epitaxial growth of nominal monolayer (ML) MoSe 2 on h-BN/Rh(111) by molecular beam epitaxy, where the MoSe 2 /h-BN layer system can be transfer… Show more

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Cited by 22 publications
(15 citation statements)
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“…The valance band structure of MoSe 2 /h-BN resembles those of the free-standing counterpart, without any evidence of interlayer hybridization. 125 The direct band gap feature of MoSe 2 is preserved in the heterostructure, and the valance band structure is similar to the calculations of free-standing monolayer MoSe 2 . 125 The interlayer interactions have enabled fascinating physics that is di±cult achieve in a single material, such as the Hofstadter's butter°y in graphene/h-BN heterostructure.…”
Section: Tmdc/h-bn Heterostructuressupporting
confidence: 69%
See 1 more Smart Citation
“…The valance band structure of MoSe 2 /h-BN resembles those of the free-standing counterpart, without any evidence of interlayer hybridization. 125 The direct band gap feature of MoSe 2 is preserved in the heterostructure, and the valance band structure is similar to the calculations of free-standing monolayer MoSe 2 . 125 The interlayer interactions have enabled fascinating physics that is di±cult achieve in a single material, such as the Hofstadter's butter°y in graphene/h-BN heterostructure.…”
Section: Tmdc/h-bn Heterostructuressupporting
confidence: 69%
“…125 The direct band gap feature of MoSe 2 is preserved in the heterostructure, and the valance band structure is similar to the calculations of free-standing monolayer MoSe 2 . 125 The interlayer interactions have enabled fascinating physics that is di±cult achieve in a single material, such as the Hofstadter's butter°y in graphene/h-BN heterostructure. 13,[126][127][128] Apart from the electron-electron interaction, the another fundamental interaction namely electron-phonon interaction also plays a dominant role in modifying the properties of the system.…”
Section: Tmdc/h-bn Heterostructuressupporting
confidence: 69%
“…[ 254 ] Besides these common materials, many reports have also focused on the growth of other 2D materials on 2D h‐BN, such as WS 2 , Bi 2 Se 3 , and ZrS 2 . [ 255–259 ]…”
Section: Applications Of 2d Iii‐nitride Materialsmentioning
confidence: 99%
“…For instance, the MoS 2 films can be fabricated with h‐BN buffer layers on the Rh(111)/Si(111) substrates. [ 92 ] The electronic properties of epitaxial MoS 2 films are proven as unintentional n‐doping semiconductors by photoemission electron momentum microscopy. Transverse heterojunctions of sub‐microscale h‐BN (monolayer)/graphene (monolayer) structures are achieved by hydrogen etching, and thereafter atmospheric‐pressure chemical vapor deposition.…”
Section: Bn Materials and Vdwhsmentioning
confidence: 99%