Electrochemical and spectrophotometric study on trivalent neodymium ion in molten binary mixtures of LiCl and alkali earth chlorides

Estimation of key physical properties for LaCl3 in molten eutectic LiCl–KCl by fitting cyclic voltammetry data to a BET-based electrode reaction kinetics model

“…Understanding these properties will allow for an effective separation of actinides from rare earth elements during the electrodeposition process and for molten salt recycling. Therefore, it is not surprising that the study of thermodynamic and transport properties of these elements in molten salt under the operating conditions of electrochemical separation has been the subject of several investigations over the past two decades [4][5][6][7][8][9].…”

Rare Earth Electrochemical Property Measurements and Phase Diagram Development in a Complex Molten Salt Mixture for Molten Salt Recycle

“…This indicates that not even all lanthanides behave identically underscoring the complexity of these studies in drawing meaningful interpretations. The closely related system of NdCl3-ACl (A = Li, Na, K, Cs) is much harder to comment on since it has been studied by only a handful of authors [88,89,90]. The NdCl3 also shows an octahedral structure with NdCl6 3-ions [88] in the presence alkali ions like Cs + .…”

Electrochemical synthesis of nanosized powders of neodymium and praseodymium hexaborides and ternary compounds based on neodymium (praseodymium), boron and iron group metals from chloride-fluoride melts.

“…Так, эти вопросы, а также определение кинетических параметров электродных процессов в низкотем-пературном хлоридном расплаве LiCl-KCl и рас-плаве LiCl-CaCl 2 являются предметом изучения японских, испанских и российских ученых [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15]. Электрохимическому получению сплавов интер-металлических соединений на основе празеоди-ма и неодима в галогенидных расплавах методом диффузионного насыщения посвящены работы [16][17][18].…”