Electrochemical and photoelectrochemical behaviour of polythiophenes in non-aqueous solutions

Semenikhin, Oleg A.; Ovsyannikova, E. V.; Ehrenburg, Maria R.; Алпатова, Н. М.; Kazarinov, V.E.

doi:10.1016/s0022-0728(00)00304-1

Cited by 44 publications

(36 citation statements)

References 28 publications

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“…4a). 19,20 The process is known as trapping effect. After n-doping at cathodic potentials the polymer keeps a chemical memory (negative charged chains-cations).…”

Section: Cation's Trapping: a Chemical Memorymentioning

confidence: 99%

Biomimetic Conducting Polymers: Synthesis, Materials, Properties, Functions, and Devices

Otero

2013

Polymer Reviews

129

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Electro-generations of conducting polymers are fast processes through a complex mechanism of parallel reactions giving mixed materials. The films are three-dimensional electrochemical reactors: reactive macromolecules, ions, and solvent. The film composition and its related properties reviewed here change by oxidation/reduction along several orders of magnitude under control. One reaction shifts different properties (multifunctionality). In one device several reaction driven tools, actuators and sensor, work simultaneously (full integration

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“…4a). 19,20 The process is known as trapping effect. After n-doping at cathodic potentials the polymer keeps a chemical memory (negative charged chains-cations).…”

Section: Cation's Trapping: a Chemical Memorymentioning

confidence: 99%

Biomimetic Conducting Polymers: Synthesis, Materials, Properties, Functions, and Devices

Otero

2013

Polymer Reviews

129

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“…curves 3, 4 and curve 0). The nature of the prepeaks and "enhanced plateau" were widely discussed in the literature and attributed to the charge trapping [85][86][87] or/and redox reaction of chemically modified polymer fragments formed due to the presence of impurities like water traces in the working solution [88].…”

Section: N-doping Of P(ednbted) In Dcmmentioning

confidence: 99%

Voltammetric, EQCM, and in situ conductance studies of p- and n-dopable polymers based on ethylenedioxythiophene and bithiazole

Sezer

Skompska

Heınze

2008

Electrochimica Acta

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“…This is shown schematically as the last equation in Scheme 1. The extraneous oxidation wave at ±1.34 V is an artifact of residual doping [19,20] and can be explained as follows.…”

Section: Full Papermentioning

confidence: 99%

A Robust Electroactive n-Dopable Aromatic Polyketone

Chiechi

Sönmez

Wudl³

2005

Adv. Funct. Mater.

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A new n‐dopable polyketone, poly[(5‐(2,5‐dihexyl‐4‐(thiophen‐2‐yl)phenyl)thiophen‐2‐yl)(4‐ketophenyl)methanone] (PTK), is synthesized via Friedel–Crafts acylation. Though insulating in the neutral state, PTK becomes conductive upon electrochemical reduction. The stable, two‐electron, fully reversible reduction is probed spectroelectrochemically and via in‐situ conductivity measurements.

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Electrochemical and photoelectrochemical behaviour of polythiophenes in non-aqueous solutions

Cited by 44 publications

References 28 publications

Biomimetic Conducting Polymers: Synthesis, Materials, Properties, Functions, and Devices

Biomimetic Conducting Polymers: Synthesis, Materials, Properties, Functions, and Devices

Voltammetric, EQCM, and in situ conductance studies of p- and n-dopable polymers based on ethylenedioxythiophene and bithiazole

A Robust Electroactive n-Dopable Aromatic Polyketone

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