2013
DOI: 10.1063/1.4815970
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Effects of humidity on performance of electric-double-layer oxide-based thin-film transistors gated by nanogranular SiO2 solid electrolyte

Abstract: Electric-double-layer oxide-based thin-film transistors gated by nanogranular SiO2 solid electrolyte have been fabricated at room temperature. The effects of humidity on performances are investigated. At the relative humidity of 65 %, the measured capacitance is 10 μF/cm2, and the device shows Ion/off ratio of 8.93 × 107, field-effect mobility of 5.9 cm2/Vs. As relative humidity declines, the measured capacitance decreases, which gives rise to the degradation in performance. Especially, at the relative humidit… Show more

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Cited by 16 publications
(17 citation statements)
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“…[31][32][33] The main drawback of such synaptic devices are the requirements of humidity to function as a synaptic FET, where the proton conductivity in the phosphorus-doped nanogranular SiO2 films is facilitated by absorbed water molecules in the nanoporous film. 33,34 Short term synaptic plasticity is demonstrated with aqueous gated Indium Gallium Zinc oxide (IGZO) synaptic devices using water and salt as gate electrolyte. 35 However, dissolution of the IGZO films in water and irreversible electrochemical reactions at interface are a major concern in these types of devices.…”
Section: Introductionmentioning
confidence: 99%
“…[31][32][33] The main drawback of such synaptic devices are the requirements of humidity to function as a synaptic FET, where the proton conductivity in the phosphorus-doped nanogranular SiO2 films is facilitated by absorbed water molecules in the nanoporous film. 33,34 Short term synaptic plasticity is demonstrated with aqueous gated Indium Gallium Zinc oxide (IGZO) synaptic devices using water and salt as gate electrolyte. 35 However, dissolution of the IGZO films in water and irreversible electrochemical reactions at interface are a major concern in these types of devices.…”
Section: Introductionmentioning
confidence: 99%
“…A possible reason for this frequency dependent capacitance is the low ionic mobility of the mobile protons in the SiO 2 dielectric. As indicated in our previous study [21], some water molecules might be absorbed from the ambient air, forming three coordinate oxygen centers, Si-OH + -Si, in the SiO 2 electrolyte [18,23]. The external electric field will force the protons to jump from one hydroxyl group to the next due to the non-stable bonding between hydrogen and oxygen.…”
Section: Introductionmentioning
confidence: 99%
“…The protons would be from the ionization of water molecules. The mechanism of H + diffusion in the MC solid electrolyte is same as that of other proton conductor films 20. The micro pores are supposed to have a columnar structure.…”
Section: Resultsmentioning
confidence: 95%