“…These lamellae can be used as base elements in heterojunctions with optical contact, structures of semiconductor‐own oxide type and metal‐semiconductor contact . Both, the specifics of chemical bonds between the atoms of B‐A‐A‐B layered packings, and low density of surface states (≈10 10 cm −2 ), define the obtaining methods of 2D structures for nano‐lamellar electronic devices, ultrathin layer transistors, etc. The thermal annealing (TA) of gallium and indium monochalcogenides in normal atmosphere, or in oxygen‐enriched atmosphere, leads to the formation of their crystalline micro and nanocomposites with In 2 O 3 and Ga 2 O 3 oxides .…”