Bi-antimony capped Keggin polyoxometalate modified with Cu-ligand fragment

Kinetics and Thermodynamics of Constitutional Dynamic Coordination Systems Based on FeII, CoII, NiII, CuII, and ZnII

“…Zinc(II) triflate [Zn(OTf) 2 ] and iron(II) perchlorate [Fe(ClO 4 ) 2 ] were chosen as suitable metal sources for the dynamic complexes, owing to their favorable solubility properties in methanol. Two different ligands were in addition chosen: 5,5′‐ and 4,4′‐substituted 2,2′‐bipyridines, expected to display relatively minor structural differences of the different complexes compared to the 3,3′‐ or 6,6′‐substituted counterparts . Crystal structures have been reported for some of the homoleptic complexes .…”

Two Layerlike Supramolecular Assemblies Based on B‐Anderson‐Type Polyanionic Clusters and Their Adsorption Property

“…[8][9][10][11][12][13][14][15][16][17][18] In our ongoing efforts to develop synthetic and functional analogues of POM-based hybrids, our recent research has focused on the synthesis of POM-based assemblies by utilizing the weak interactions. [19][20][21] In these assemblies, a number of molecular components are held together by means of noncovalent intermolecular contacts, which can potentially combine the advantages of inorganic oxometal clusters and organic molecules through structural fine-tuning. Compared to widely reported pseudo-spherical Keggin-and Dawson-type anions, which can easily lead to the formation of the hybrid assemblies with a "core-shell" inclusion structure, investigation into organic-inorganic hybrids that use Anderson-type polyanions as building blocks is relatively rare.…”