A novel aluminum-containing, bimolybdenum-capped Keggin-type polyoxomolybate cluster of the {AlMo12O40(MoO2)2} anion has been synthesized and characterized. This is the first experimentally determined Keggin-type {AlMo12O40} polyoxoanion. The polyoxometalate crystal exhibits high selectivity toward the heterogeneous catalytic oxidation of cyclohexanol to cyclohexanone.
(2) [bpp = 1,3-di(4-pyridyl)propane; bpe = 1,2-di(4-pyridyl)ethylene] have been synthesized and characterized. X-ray diffraction analysis reveals that the supramolecular structures of two compounds are built upon alternative arrangements of inorganic anionic and organic cationic layers. In 1 and 2 the oxophile silver centers have dif-
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