An Experimental and Kinetic Study of the Sorption of Carbon Dioxide onto Amine-Treated Oil Fly Ash

Saad, Mohammed A.; Al–Marri, Mohammed J.; Yaumi, Ali L.; Hussein, Ibnelwaleed A.; Shawabkeh, Reyad

doi:10.1155/2016/6021798

Cited by 9 publications

(5 citation statements)

References 48 publications

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“…Δ G ads , Δ H ads , and Δ S ads values for pure and treated with surfactant carbonate are computed in Table . Negative Δ H ads values confirm the exothermic nature of CH 4 and CO 2 adsorption on pure carbonate. , At 50 °C the values of Δ G ads for CO 2 and CH 4 on pure carbonate are less than that of treated limestone underlining high adsorption spontaneity . As the temperature was raised to 100 and 150 °C, the values of Δ G ads for CO 2 and CH 4 on treated carbonate decreases revealed the favored spontaneity at 100 and 150 °C because thermal energy is higher than adsorption energy.…”

Section: Results and Discussionmentioning

confidence: 75%

“…49,50 At 50 °C the values of ΔG ads for CO 2 and CH 4 on pure carbonate are less than that of treated limestone underlining high adsorption spontaneity. 51 As the temperature was raised to 100 and 150 °C, the values of ΔG ads for CO 2 and CH 4 on treated carbonate decreases revealed the favored spontaneity at 100 and 150 °C because thermal energy is higher than adsorption energy. Correspondingly, these findings suggest that at a temperature range of 100−150 °C (which is the range for most of the gas reservoirs), the adsorption of CO 2 is much more preferred to that of CH 4 , which can be attributed to the high selectivity and affinity of calcite minerals toward capturing CO 2 .…”

Section: Methodsmentioning

confidence: 95%

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Impact of Surfactant on the Retention of CO₂ and Methane in Carbonate Reservoirs

et al. 2018

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Enhanced gas recovery methods such as foamed CO 2 are recommended for depleted gas reservoirs. Viscoelastic surfactant (VES) is a form of a surfactant used for forming CO 2 foam. In this study, the impact of VES on CH 4 and CO 2 retention and adsorption in calcite rock samples was studied. Crushed samples of Indiana limestone rocks of average particle size (125−250 μm) were used in the static adsorption experiments. To study the effect of VES on CH 4 and CO 2 adsorption, 50% of the crushed samples were conditioned in a solution of NaCl of 0.1 vol % surfactant. X-ray diffraction shows that the rock samples are 99.99% calcite and traces of quartz. The gas adsorption experiments were performed at different temperatures; namely; 50, 100, and 150 °C and at a pressure of 45 bar. At 50 °C, the plain calcite samples adsorbed more CH 4 and CO 2 compared to that treated with VES. However, at 100 and 150 °C, the plain sample adsorbed much less CH 4 and CO 2 than the treated sample. This means that at higher temperatures (100 and 150 °C) VES enhanced the adsorption of both CO 2 and CH 4 on the rock surface. Thermodynamic investigations showed that the process of gas adsorption in the plain samples was exothermic with ΔH ads of −13.5 and −16.7 kJ/mol for CO 2 and CH 4 , respectively, and at 50 °C the adsorption was spontaneous with ΔG ads of −0.425 for CH 4 and −2.599 for CO 2 . In contrast, at higher temperatures (100 and 150 °C), the adsorption of CO 2 and CH 4 on surfactant treated sample was spontaneous and endothermic with corresponding ΔH ads of 36.2 and 60.1 kJ/mol and ΔG ads of −4.701 and −0.581 for CO 2 and CH 4 , respectively. The adsorption of CO 2 was three times that of CH 4 because of the high affinity of calcite to CO 2 . Because of the multilayer adsorption on both samples, Freundlich isotherm was found to be the best model that fits the experimental data of calcite with both CO 2 and CH 4 at different temperatures. Dynamic adsorption experiments were carried out using gas coreflooding system with the same calcite cores used in the static adsorption experiments. The results of this study showed that carbonate rock samples conditioned in the surfactant solution have great adsorption potential for CO 2 and are excellent candidates for CO 2 sequestration. However, surfactant promoted high CH 4 adsorption at 100 and 150 °C, and this will reduce the natural gas recovery. In contrast, using viscoelastic surfactant at low-temperature reservoirs (50 °C) reduced CH 4 adsorption by blocking the active adsorption sites in the carbonate rock samples, and this will increase the gas recovery.

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Section: Results and Discussionmentioning

confidence: 75%

Section: Methodsmentioning

confidence: 95%

Impact of Surfactant on the Retention of CO₂ and Methane in Carbonate Reservoirs

et al. 2018

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“…The selective adsorption of CO 2 from a CO 2 /N 2 mixture utilizing previously discussed AC was investigated by Yaumi et al [44] while the sorption kinetic study was conducted by Saad et al [102] It was reported that the maximum adsorption capacity of 240 mg g À 1 was achieved using chemically treated HFOA. It was also stated that the adsorption was dependent on the CO 2 concentration, gas flow rate, and temperature and humidity, as it increased with an increase in these parameters.…”

Section: P E R S O N a L A C C O U N T T H E C H E M I C A L R E C O R Dmentioning

confidence: 99%

Characterization, Processing, and Application of Heavy Fuel Oil Ash, an Industrial Waste Material – A Review

Basha

Aziz

Maslehuddin

et al. 2020

The Chemical Record

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Heavy fuel oil ash (HFOA) is generated as an industrial waste material during the combustion of heavy fuel oil in power/desalination plants. With increasing energy demands, a significant volume of HFOA is generated. It is generally disposed of in landfills, causing environmental pollution, as it contains several toxic elements. Recently, efforts were made towards developing strategies for reusing industrial waste materials and creating value-added products from the waste materials. Despite significant information available in the literature on the utilization of HFOA, there is still a need for a thorough and systematic review on the characterization and utilization of HFOA in various applications. Consequently, this paper aims to present a critical review of the literature on HFOA generation, its chemical composition, physical properties, morphology, and applications. It is encouraging to note that HFOA has been used in several potential applications, such as the preparation of activated carbon and carbon nanotubes, metal recovery, environmental pollutant removal, polymer composites and construction materials, etc. However, the development of several value-added materials utilizing HFOA and its applications in other areas such as coatings, cathodic protection systems, and phase change materialswould emerge as a new topic of research. It is expected that this review will act as a precursor for further research on the use of HFOA in industrial applications. Since the use of HFOA will lead to environmental, economic, and technical benefits, research in the utilization of this industrial waste material is highly recommended.

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“…The sorption studies evaluated 1.3 mmol g −1 of CO 2 at 25°C [31]. In a similar study, the activated carbon produced from waste oil fly ash was used as CO 2 adsorbent by Saad et al [32]. The carbon material was used to capture CO 2 (74.5 mg g −1 ) from a mixture of N 2 and CO 2 and the chemisorbed amount of the gas increased over a temperature range, 0-40°C.…”

Section: Introductionmentioning

confidence: 99%

Efficient CO₂ adsorption using mesoporous carbons from biowastes

Sriram

Supriya²,

Kurkuri

et al. 2019

Mater. Res. Express

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The mesoporous carbon nanomaterials obtained from waste onion peels confirmed the formation of mesoporous carbon nanospheres (CNSs) with an average pore diameter of 2 nm. The as obtained CNSs were studied to demonstrate their ability to adsorb the greenhouse gas CO 2 at different temperatures, 30, 40 and 50°C. The results showed that the CNSs have high potential to adsorb CO 2 at these temperatures. Present work demonstrates the formation of sustainable, porous adsorbents by a simple waste to wealth based approach that is effective for the adsorption of CO 2 .

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An Experimental and Kinetic Study of the Sorption of Carbon Dioxide onto Amine-Treated Oil Fly Ash

Cited by 9 publications

References 48 publications

Impact of Surfactant on the Retention of CO₂ and Methane in Carbonate Reservoirs

Impact of Surfactant on the Retention of CO₂ and Methane in Carbonate Reservoirs

Characterization, Processing, and Application of Heavy Fuel Oil Ash, an Industrial Waste Material – A Review

Efficient CO₂ adsorption using mesoporous carbons from biowastes

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An Experimental and Kinetic Study of the Sorption of Carbon Dioxide onto Amine-Treated Oil Fly Ash

Cited by 9 publications

References 48 publications

Impact of Surfactant on the Retention of CO2 and Methane in Carbonate Reservoirs

Impact of Surfactant on the Retention of CO2 and Methane in Carbonate Reservoirs

Characterization, Processing, and Application of Heavy Fuel Oil Ash, an Industrial Waste Material – A Review

Efficient CO2 adsorption using mesoporous carbons from biowastes

Contact Info

Product

Resources

About

Impact of Surfactant on the Retention of CO₂ and Methane in Carbonate Reservoirs

Impact of Surfactant on the Retention of CO₂ and Methane in Carbonate Reservoirs

Efficient CO₂ adsorption using mesoporous carbons from biowastes