Sensors have become integral part of our lives. Electrochemical sensors are the oldest and the most commercially used sensors. Biomass carbonization by pyrolysis and hydrothermal methods are discussed as a cost-effective strategy for fabrication of electrodes for electrochemical sensing applications. Porosity and surface area along with graphitic nature of bio derived carbon materials greatly affects the performance of electrochemical sensors. Various techniques are used to improve the surface properties so as to enhance the electrocatalytic behavior of working electrodes. Synthetic and bioderived carbon materials are compared for their electrochemical sensing applications.
Carbon nanospheres derived from a natural source using a green approach were reported. Lablab purpureus seeds were pyrolyzed at different temperatures to produce carbon nanospheres for supercapacitor electrode materials. The synthesized carbon nanospheres were analyzed using SEM, TEM, FTIR, TGA, Raman spectroscopy, BET and XRD. They were later fabricated into electrodes for cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy testing. The specific capacitances were found to be 300, 265 and 175 F g in 5 M KOH electrolyte for carbon nanospheres synthesized at 800, 700 and 500 °C, respectively. These are on a par with those of prior electrodes made of biologically derived carbon nanospheres but the cycle lives were remarkably higher than those of any previous efforts. The electrodes showed 94% capacitance retention even after 5200 charge/discharge cycles entailing excellent recycling durability. In addition, the practical symmetrical supercapacitor showed good electrochemical behaviour under a potential window up to 1.7 V. This brings us one step closer to fabricating a commercial green electrode which exhibits high performance for supercapacitors. This is also a waste to wealth approach based carbon material for cost effective supercapacitors with high performance for power storage devices.
Surface properties always play a dominant role in the energy storage devices. Understanding the surface phenomena is the key to tune the energy storage device using biowaste based porous nano carbons. Here, Callerya atropurpurea pod derived peculiar porous nanocarbons are synthesized by pyrolysis at different temperatures without any synthetic templates approach. Elaborate analysis of surface textures on the effect of pore size, volume and specific surface area on specific capacitance and frequency response behavior of nanocarbons were studied in detail. Electrochemical characterizations establish the mutuality of porosity and microtextural properties of nanocarbons with specific capacitance.The electrochemical characterization of the novel materials as supercapacitor electrode shows a high specific capacitance of 326.54 F g −1 at 0.25 A g −1 in 1.0 M KOH. A practical symmetric supercapacitor device is fabricated with a specific capacitance of 86.38 F g −1 at 0.1 A g −1 , and high energy density of 27.0 Wh kg −1 . This symmetric supercapacitor also possesses outstanding capacitance retention of 92.16% for 5000 charge discharge cycles and also stability of 97.17%, after voltage holding at the maximum voltage for 100 hours. Present manuscript gives the strong evidence for structure-property relationships so that one can tune the energy storage devices effectively.
A new heterogeneous catalyst was synthesized by immobilizing Pd on areca nut kernel‐derived carbon nanospheres (CNSs). The CNSs, without any further activation processes, accommodated 3% of Pd on their surface. The new Pd/CNS material was used for the reduction of nitroarenes and Suzuki–Miyaura coupling of bromoarenes with aryl boronic acids. The reactions were conducted under microwave irradiation at 160 °C using 12 mol% of Pd/CNS (0.36% actual Pd content). The reduction of nitroarenes into their respective amino compounds was achieved in 10–20 min (conversion up to 100%); by contrast, the Suzuki–Miyaura reactions yielded up to 98% at 150 °C with 10 mol% of Pd/CNS catalyst. The products were identified using gas chromatography and nuclear magnetic resonance spectroscopy. The catalyst was isolated from reaction mixture and reused without any significant loss in the activity. Thus, the present work introduces one‐pot‐derived porous CNSs as efficient catalytic support to Pd, establishing an alternative to existing Pd/C in terms of cost and efficiency.
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