“…The initial paraelectric phase of TlInS 2 and TlGaSe 2 is characterized by the space symmetric group of C 6 2h . PT into IC -phase is accompanied by a soft mode condensation (at T i = 216 K and 120 K, respectively) with the wave vector q i = (δ, δ, 0.25) in the Brillouin zone, where δ is the incommensurate parameter [13]. At T c ∼ 201 K and 107 K, respectively the δ value jumps to zero, and the crystals TlInS 2 and TlGaSe 2 exhibit a structural PT to commensurate ferroelectric phase with the wave vector of q c = (0, 0, 0.25) [25][26][27][28][29].…”