A Thermodynamic Study of the Tin—Bismuth System

Seltz, Harry; Dunkerley, F. J.

doi:10.1021/ja01258a044

Cited by 45 publications

(9 citation statements)

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“…However, the calculated enthalpies showed large mutual discrepancies. Only those of Seltz and Dunkerley [18] were in good agreement with directly measured data [12][13][14]. Enthalpies of formation of solid alloys are also available from the calorimetric measurements made by Oelsen and Golücke [9].…”

Section: Bi-sn Systemsupporting

confidence: 63%

Thermodynamic assessment of the Bi–Sn–Zn System

Vízdal

Braga

Kroupa

et al. 2007

Calphad

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A thermodynamic assessment of the Bi-Sn-Zn ternary system was carried out using the CALPHAD approach along with thermodynamic descriptions from new assessments of the Bi-Sn and Bi-Zn systems. Selected experimental data from the literature and our own work were also used. New sets of optimized thermodynamic parameters were obtained that lead to a very good fit between the calculated and experimental data. The Bi-Sn-Zn system is one of the candidates for lead-free solder materials.

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Section: Bi-sn Systemsupporting

confidence: 63%

Thermodynamic assessment of the Bi–Sn–Zn System

Vízdal

Braga

Kroupa

et al. 2007

Calphad

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“…25,26 The results of the different measurements show large scatter and some contradictions. More recent experimental results by emf measurement given by Asryan and Mikula 26 have shown that the enthalpy of mixing versus composition was asymmetric.…”

Section: Silver-bismuth Systemmentioning

confidence: 99%

Thermodynamic Properties of Liquid Ag-Bi-Sn Alloys

Knott

Mikula

2006

Journal of Elec Materi

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As a promising lead-free solder, the thermodynamic properties of the liquid ternary Ag-Bi-Sn system were investigated. Using an appropriate galvanic cell, the partial free energies of Sn in liquid Ag-Bi-Sn alloys were determined as a function of concentration and temperature. Thermodynamic properties were obtained for 27 alloys. Their composition was situated on three cross sections with the constant ratios of Ag:Bi = 2:1, 1:1, and 1:2. The integral Gibbs free energy and the integral enthalpy for the ternary system at 900 K were calculated by Gibbs-Duhem integration.

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“…... (1) where V, Φ*, and n 1/3 are the parameters, P, Q and R are the so-called constants determined by Miedema. P and Q were just determined empirically from the experimental enthalpy data.…”

Section: Subregular Modelmentioning

confidence: 99%

Calculated mixing enthalpies of 11 IIB-IVB and IIB-VB binary alloy systems using a subregular model

Zhang¹,

Shu²,

Liao³

et al. 2010

J min metall B Metall

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There have been no theoretical calculations of the mixing enthalpies for group B metal alloy systems using the famous Miedema theory or from first principles. Therefore such systematic calculations for the 11 group IIB－IVB and IIB－VB binary alloy systems are performed for the first time using a subregular model. The results show that the agreement between the calculations and experimental data is pretty good and could be accepted from the theoretical or experimental points of view. It can be concluded from the results that the subregular model can be used for calculating the mixing enthalpies of the group B alloy systems, at least for the IIB－IVB and IIB－VB alloy systems

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A Thermodynamic Study of the Tin—Bismuth System

Cited by 45 publications

References 0 publications

Thermodynamic assessment of the Bi–Sn–Zn System

Thermodynamic assessment of the Bi–Sn–Zn System

Thermodynamic Properties of Liquid Ag-Bi-Sn Alloys

Calculated mixing enthalpies of 11 IIB-IVB and IIB-VB binary alloy systems using a subregular model

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