2019
DOI: 10.1007/s10600-019-02653-3
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A New Alkaloid from Delphinium leptocarpum

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Cited by 6 publications
(4 citation statements)
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“…The indolinopyrrole fragment is bound to the hetisine-type C 20 -DA part through an a-directed (relative to the indoline core) C-17-C-3 bond according to an Xray crystal structure analysis. 19 In addition, several of the new alkaloids possess at least one uncommon substituent. For example, new C 18 -DAs 1 and 2 possess an uncommon 3,4epoxide unit, 20,21 and new alkaloids 35 and 71 have an N-C (19) ] O lactam group.…”
Section: Alkaloidsmentioning
confidence: 99%
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“…The indolinopyrrole fragment is bound to the hetisine-type C 20 -DA part through an a-directed (relative to the indoline core) C-17-C-3 bond according to an Xray crystal structure analysis. 19 In addition, several of the new alkaloids possess at least one uncommon substituent. For example, new C 18 -DAs 1 and 2 possess an uncommon 3,4epoxide unit, 20,21 and new alkaloids 35 and 71 have an N-C (19) ] O lactam group.…”
Section: Alkaloidsmentioning
confidence: 99%
“…19 In addition, several of the new alkaloids possess at least one uncommon substituent. For example, new C 18 -DAs 1 and 2 possess an uncommon 3,4epoxide unit, 20,21 and new alkaloids 35 and 71 have an N-C (19) ] O lactam group. 22,23 New alkaloids 33, 62 and possess an imine group at C-19, 23,24 while alkaloid 92 has an imine group at C-17, a rare substituent position.…”
Section: Alkaloidsmentioning
confidence: 99%
“…Their data demonstrated the presence of 10 diterpenoid alkaloids in the extracts of the plant, including lycoctonine, caerudelphinine A, talitine A-C, tatsienine-V, d-magnoflorine, vakhmatine, delatisine, and a propionate derivative (28). Kurbanov et al revealed that the aerial parts of D. leptocarpum during flowering season possessed a new alkaloid compound with a formula of C 34 H 43 N 3 O 3 that was called leptanine (53). The genus D. delavayi Franch has been described to contain several diterpenoid alkaloid compounds; however, deltaline with formula C 27 H 41 NO 8 is a major C19-diterpenoid alkaloid isolated from the root extracts of Delphinium sp.…”
Section: Traditional Applicationmentioning
confidence: 99%
“…According to X-ray crystal structure analysis, the indolinonepyrrole fragment was bound to the hetisine-type C 20 -DA part through an a-directed (relative to the indoline core) C (17) -C (3 0 ) covalent bond. 98 Vakognavine-type C 20 -DAs (C-2) have an N-C (19) seco hetisine skeleton in addition to a formyl group at C-4. During the past forty years, 17 new vakognavines were isolated from 6 Delphinium species (Fig.…”
Section: -Diterpenoid Alkaloidsmentioning
confidence: 99%