2016 IEEE 66th Electronic Components and Technology Conference (ECTC) 2016
DOI: 10.1109/ectc.2016.141
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6um Pitch High Density Cu-Cu Bonding for 3D IC Stacking

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Cited by 18 publications
(5 citation statements)
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“…Since Cu formate is hydrophilic, the second study investigated the impacts of chip-storage conditions and time on the degradation of Cu-formate layer. Xie et al used Cu formate to protect surfaces from oxidation during chip handling in a production line for Cu–Cu bonding, and reported its stability for a few hours [ 16 ]. We investigated the lifetime of Cu formate by storing the chips for different durations in nitrogen and dry-air cabinets.…”
Section: Resultsmentioning
confidence: 99%
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“…Since Cu formate is hydrophilic, the second study investigated the impacts of chip-storage conditions and time on the degradation of Cu-formate layer. Xie et al used Cu formate to protect surfaces from oxidation during chip handling in a production line for Cu–Cu bonding, and reported its stability for a few hours [ 16 ]. We investigated the lifetime of Cu formate by storing the chips for different durations in nitrogen and dry-air cabinets.…”
Section: Resultsmentioning
confidence: 99%
“…The temperature profile for the formic-acid-based reduction process is shown as the upper curve in Figure 4 b. This reduction process is already very efficient at lower temperatures, and the reaction took place as follows [ 16 ]: where HCOOH is formic acid and Cu(HCOO) 2 is Cu formate. At ambient conditions, Cu formate is formed, being temporarily stable below 140 °C, and starts decomposing at about 140 °C [ 16 ].…”
Section: Methodsmentioning
confidence: 99%
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“…The elimination of solder by direct metal-metal bonding also provides opportunities for ultra-fine pitch interconnects. 6 µm interconnect pitch with 3 µm copper pillars were demonstrated in [21] using direct Cu-Cu TCB process.…”
Section: A Interconnect Technologymentioning
confidence: 99%