228. Reactions of bistrifluoromethylthiomercury and trifluoromethylthiomercuric chloride

Emeléus, H. J.; Pugh, Henry L.

doi:10.1039/jr9600001108

Cited by 15 publications

(5 citation statements)

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“…Its chemistry has been reviewed (105,196,230). Its infrared (109), Raman (90), and n.m.r. (167) spectra have been recorded and interpreted.…”

Section: Miscellaneous O-trihalomethyl Compoundsmentioning

confidence: 99%

“…With bis(trifluoromethyl)iodophosphine, bis(trifluoromethylthio)mercury forms bis(trifluoromethyl) trifluoromethyl thiophosphine. The arsenic analog reacts accordingly (109).…”

Section: Miscellaneous O-trihalomethyl Compoundsmentioning

confidence: 99%

“…(CFaS)íHg + HgCl2 -> 2CF3SHgCl Its infrared spectrum has been recorded and interpreted. With silver nitrate or acetate it forms trifluoromethylthiomercury nitrate and acetate, respectively (109).…”

Section: Miscellaneous O-trihalomethyl Compoundsmentioning

confidence: 99%

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N-, O-, and S-Trihalomethyl Compounds

Senning¹

1965

Chem. Rev.

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“…Its chemistry has been reviewed (105,196,230). Its infrared (109), Raman (90), and n.m.r. (167) spectra have been recorded and interpreted.…”

Section: Miscellaneous O-trihalomethyl Compoundsmentioning

confidence: 99%

“…With bis(trifluoromethyl)iodophosphine, bis(trifluoromethylthio)mercury forms bis(trifluoromethyl) trifluoromethyl thiophosphine. The arsenic analog reacts accordingly (109).…”

Section: Miscellaneous O-trihalomethyl Compoundsmentioning

confidence: 99%

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N-, O-, and S-Trihalomethyl Compounds

Senning¹

1965

Chem. Rev.

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“…10,78 (gcf. 13,02); P 9,27 (9,32) + ( 3 ) ; 183, CF,SPSF+ (2); 164, CF3SPS+ (3); 151, CF,SPF+ (23); 114, PS2F+ (2); 101, CF,S+ (12); 96, PS2+ (6); 88, CF,+ (4); 82, CSF,+ (40); 69, CF,+ (60); 63, PS+ (100); 50, PFf, CF,+ (4); 44, CS+ (2); 32, S+ (8); 31, P+ (7). D a r s t e l l u n g v o n (CF&IS)nPCl,-n u n d (CFC1zS)nPC1,-, (n + 1, 2) Die Synthese dieser vier Stoffe erfolgt nach einem cinheitlichen Verfahren, das nachfolgend angegeben wird.…”

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Darstellung und Eigenschaften von Perfluorchlormethylmercaptophosphoryldichloriden und ‐chlorphosphanen

Hass

Winkler

1980

Zeitschrift anorg allge chemie

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Umsetzungen von CFnCl3−nSCl mit ROPCl2 (RCH3, C2H5) bzw. P4 führen zu CFnCl3−nSP(O)Cl2 (n = 3, 2, 1, 0) bzw. (CFnCl3−nS)XPCl3−x (n = 3, 2, 1 und x = 1, 2), die durch Elementaranalyse, IR, Massen‐, 19F und 31P‐NMR‐Spektren charakterisiert werden konnten. Bei der Thermolyse von CFn′Cl3−n′SP(O)Cl2 (n′ = 2, 1, 0) entstehen P(O)Cl3 und SCFn′Cl2−n′. SCF2 reagiert mit P(O)Cl3 zu P(O)F3. Ein Cl/Br Austausch konnte zwischen CfnCl3−nSP(O)Cl2 (n = 3, 2) und PBr3 19F und 31P‐NMR‐specktroskopisch nachgewiesen werden. Umsetzungen von (CFnCl3−nS)x PCl3−x (n = 3, 2, 1 und x = 1, 2) mit CFnCl3−nSCl (n = 3, 2, 1, 0) führen zu PCl3 und entsprechenden Disulfanen.

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“…A similar reaction occurs with allylthiol (8). Phosphorus and arsenic trichlorides react with bis(trifluoromethy1thio) mercury to give the compounds (CF,S),MCl, -, , x = 1, 2, or 3, depending on the stoichiometry of the reactants (9). No mixed pentafluorophenylthio chloro derivatives of phosphorus or arsenic, Can.…”

mentioning

confidence: 99%

Preparation and Properties of some Non-Metallic Derivatives of Pentafluorothiophenol

Peach¹,

Spinney²

1971

Can. J. Chem.

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Various non-metallic derivatives of pentafluorothiophenol, containing sulfur bonded to boron, carbon, silicon, germanium, phosphorus, arsenic, antimony, sulfur, and chlorine, have been prepared, mainly from the reaction of Pb(SC6F5), with a non-metallic halide, and characterized. The 19F n.m.r. spectra have been examined. The coordinating power of sulfur attached to a C6F5 group is minimal.Divers derives non-m6talliques du pentafluorothioph6nol contenant du soufre li6 au bore, au carbone, au silicium, au germanium, au phosphore, A I'arsenic, a I'antimoine, au soufre, et au chlore ont ett prkparb, principalement par reaction de Pb(SC6F,), avec des halogknures non-mktalliques et caractCris6s. Les spectres r.m.n. de 19F ont Bte examines. Le pouvoir de coordination du soufre attach6 a un groupe C6F5 est minimal.

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228. Reactions of bistrifluoromethylthiomercury and trifluoromethylthiomercuric chloride

Cited by 15 publications

References 0 publications

N-, O-, and S-Trihalomethyl Compounds

N-, O-, and S-Trihalomethyl Compounds

Darstellung und Eigenschaften von Perfluorchlormethylmercaptophosphoryldichloriden und ‐chlorphosphanen

Preparation and Properties of some Non-Metallic Derivatives of Pentafluorothiophenol

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