We have performed an extensive study of GaAs, Al022Gao 7sAs, and Ino 16Ga0 s4As grown using tertiarybutylarsine (TBA) in an ultra-high purity metalorganic chemical vapor deposition multi-wafer reactor. Key results include: high purity TBA A1GaAs layers with the lowest p-type carrier concentrations (4 • 1014 cm -3) reported to date; 4K photoluminescence bound exciton linewidths as narrow as 4.3 meV; C, O. Si, and S concentrations below the secondary ion mass spectrometry detection limit; and InGaAs/GaAs quantum wells with 20K PL linewidths as narrow as 3.5 meV. We also observe a strong dependence of growth rates and doping efficiency on group-V partial pressure, possibly due to a competition between excess group-V species and group-III or Si species for group-III surface sites. Finally, we demonstrate record uniformity using TBA with an A1GaAs thickness variation of only +1.4% across a 4 inch wafer.