An improved chemical one-step method (ICOSM) was used to prepare highly conductive and magnetic polypyrrole/γ-Fe2O3 (PPy/γ-Fe2O3) nanospheres ∼80 nm in diameter. In the reaction process involved, FeCl3 acts as an oxidant for the polymerization of pyrrole and as a source of FeIII for the formation of γ-Fe2O3, which also requires the initial presence of FeII, provided by the addition of FeCl2. The method differs from the previous chemical one-step method (COSM) through the addition of p-toluenesulfonic acid (p-TSA) as the dopant after addition of the FeCl3 solution was finished. The conductive and magnetic properties of PPy/γ-Fe2O3 nanospheres increased and reached maximum values simultaneously with increasing amounts of FeCl2, contrary to the result observed in the previous COSM. The resulting electromagnetic PPy/γ-Fe2O3 nanospheres show maximum conductivity of 64.4 S/cm and saturation magnetization of 4.85 A m2/kg. The p-TSA dopant plays a critical role in the formation of PPy/γ-Fe2O3 nanospheres.
Under dehumidifying conditions, the condensed water will directly affect the heat transfer and resistance characteristics of a fin-and-tube heat exchanger. The geometrical form of condensed water on fin surfaces of three different fin materials (i.e., copper fin, aluminum fin, and aluminum fin with hydrophilic layer) in a fin-and-circular-tube heat exchanger was experimentally studied in this paper. The effect of the three different fin materials on heat transfer and friction performance of the heat exchanger was researched, too. The results show that the condensation state on the surface of copper fin and aluminum fin are dropwise condensation. The condensation state on the surface of the aluminum fin with the hydrophilic layer is film condensation. For the three different material fins, increasing the air velocity (ua,in) and relative humidity (RHin) of the inlet air can enhance the heat transfer of the heat exchanger. Friction factor (f) of the three different material fins decreases with the increase of ua,in, however, increases with the increase of RHin. At the same ua,in or RHin, Nusselt number (Nu) of the copper fin heat exchanger is the largest and Nu of the aluminum fin with hydrophilic layer is the smallest, f of the aluminum fin heat exchanger is the largest and f of the aluminum fin with hydrophilic layer is the smallest. Under the identical pumping power constrain, the comprehensive heat transfer performance of the copper fin heat exchanger is the best for the studied cases.
To investigate the effects of rumen-protected choline (RPC) and rumen-protected nicotinamide (RPM) on liver metabolic function based on transcriptome in periparturient dairy cows, 10 healthy Holstein dairy cows with similar parity were allocated to RPC and RPM groups (n = 5). The cows were fed experimental diets between 14 days before and 21 days after parturition. The RPC diet contained 60 g RPC per day, and the RPM diet contained 18.7 g RPM per day. Liver biopsies were taken 21 days after calving for the transcriptome analysis. A model of fat deposition hepatocytes was constructed using the LO2 cell line with the addition of NEFA (1.6 mmol/L), and the expression level of genes closely related to liver metabolism was validated and divided into a CHO group (75 μmol/L) and a NAM group (2 mmol/L). The results showed that the expression of a total of 11,023 genes was detected and clustered obviously between the RPC and RPM groups. These genes were assigned to 852 Gene Ontology terms, the majority of which were associated with biological process and molecular function. A total of 1123 differentially expressed genes (DEGs), 640 up-regulated and 483 down-regulated, were identified between the RPC and RPM groups. These DEGs were mainly correlated with fat metabolism, oxidative stress and some inflammatory pathways. In addition, compared with the NAM group, the gene expression level of FGF21, CYP26A1, SLC13A5, SLCO1B3, FBP2, MARS1 and CDH11 in the CHO group increased significantly (p < 0.05). We proposed that that RPC could play a prominent role in the liver metabolism of periparturient dairy cows by regulating metabolic processes such as fatty acid synthesis and metabolism and glucose metabolism; yet, RPM was more involved in biological processes such as the TCA cycle, ATP generation and inflammatory signaling.
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