Graphitic carbon nitrides (g-C3N4) with unique physicochemical properties are promising candidates for photocatalysis applications. However, pristine g-C3N4 often suffers from narrow absorption ranges and high carrier recombination rates, which result...
Metal‐halide perovskites have drawn profuse attention during the past decade, owing to their excellent electrical and optical properties, facile synthesis, efficient energy conversion, and so on. Meanwhile, the development of information storage technologies and digital communications has fueled the demand for novel semiconductor materials. Low‐dimensional perovskites have offered a new force to propel the developments of the memory field due to the excellent physical and electrical properties associated with the reduced dimensionality. In this review, the mechanisms, properties, as well as stability and performance of low‐dimensional perovskite memories, involving both molecular‐level perovskites and structure‐level nanostructures, are comprehensively reviewed. The property–performance correlation is discussed in‐depth, aiming to present effective strategies for designing memory devices based on this new class of high‐performance materials. Finally, the existing challenges and future opportunities are presented.
Solar‐driven photothermal water evaporation is considered an elegant and sustainable technology for freshwater production. The existing systems, however, often suffer from poor stability and biofouling issues, which severely hamper their prospects in practical applications. Conventionally, photothermal materials are deposited on the membrane supports via vacuum‐assisted filtration or dip‐coating methods. Nevertheless, the weak inherent material‐membrane interactions frequently lead to poor durability, and the photothermal material layer can be easily peeled off from the hosting substrates or partially dissolved when immersed in water. In the present article, the discovery of the incorporation of borophene into cellulose nanofibers (CNF), enabling excellent environmental stability with a high light‐to‐heat conversion efficiency of 91.5% and water evaporation rate of 1.45 kg m−2 h−1 under simulated sunlight is reported. It is also demonstrated that borophene papers can be employed as an excellent active photothermal material for eliminating almost 100% of both gram‐positive and gram‐negative bacteria within 20 min under three sun irradiations. The result opens a new direction for the design of borophene‐based papers with unique photothermal properties which can be used for the effective treatment of a wide range of wastewaters.
Single-metal-atom catalysts (SMACs) with the merits of maximum atom utilization, peculiar electronic structure, and adjustable coordination environment, have emerged as the rising stars. They are not only regarded as the promising electrocatalysts, but also show unconventionally excellent alkali storage, thus enabling them for energy devices. In this work, we review the up-to-date progress of single metal atom catalysts including the detailed synthetic strategies and all sorts of applications in energy storage and conversion. In addition, we also discuss intrinsic catalytic effects, degradation mechanism, modulation approaches, support structure design, current challenges, and potential development trends. This work may shed light on developing high-performance SMACs using a variety of strategies for catalytic and energy applications.
Porous boron carbon nitride (BCN) is one of the exciting systems with unique electrochemical and adsorption properties. However, the synthesis of low-cost and porous BCN with tunable porosity is challenging, limiting its full potential in a variety of applications. Herein, the preparation of well-defined mesoporous boron carbon nitride (MBCN) with high specific surface area, tunable pores, and nitrogen contents is demonstrated through a simple integration of chemical polymerization of readily available sucrose and borane ammonia complex (BAC) through the nano-hard-templating approach. The bimodal pores are introduced in MBCN by controlling the self-organization of BAC and sucrose molecules within the nanochannels of the template. It is found that the optimized sample shows a high specific capacitance (296 F g −1 at 0.5 A g −1 ), large specific capacity for sodium-ion battery (349 mAg h −1 at 50 mAh g −1 ), and excellent CO 2 adsorption capacity (27.14 mmol g −1 at 30 bar). B-C, B-N, C-N, and C-C) and the large specific surface area strongly support the high adsorption capacity. This finding offers an innovative breakthrough in the design and development of MBCN nanostructures for energy storage and carbon capture applications.
Density functional theory calculations demonstrate that different adsorption sites (
Surface acoustic waves (SAWs)-matter interaction provides a fascinating doorknob for inducing and manipulating novel phenomena and functionalities in two-dimensional (2D) materials. The dynamic strain field and piezo-electric field associated with...
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