Abstract. In order to investigate the formation and growth processes of nucleation mode particles, and to quantify the particle number (PN) concentration and size distributions in Hong Kong, an intensive field measurement was conducted from 25 October to 29 November in 2010 near the mountain summit of Tai Mo Shan, a suburban site approximately the geographical centre of the New Territories in Hong Kong. Based on observations of the particle size distribution, new particle formation (NPF) events were found on 12 out of 35 days with the estimated formation rate J 5.5 from 0.97 to 10.2 cm −3 s −1 , and the average growth rates from 1.5 to 8.4 nm h −1 . The events usually began at 10:00-11:00 LT characterized by the occurrence of a nucleation mode with a peak diameter of 6-10 nm. Solar radiation, wind speed, sulfur dioxide (SO 2 ) and ozone (O 3 ) concentrations were on average higher, whereas temperature, relative humidity and daytime nitrogen dioxide (NO 2 ) concentration were lower on NPF days than on non-NPF days. Back trajectory analysis suggested that in majority of the NPF event days, the air masses originated from the northwest to northeast directions. The concentrations of gaseous sulfuric acid (SA) showed good power-law relationship with formation rates, with exponents ranging from 1 to 2. The result suggests that the cluster activation theory and kinetic nucleation could potentially explain the observed NPF events in this mountainous atmosphere of Hong Kong. Meanwhile, in these NPF events, the contribution of sulfuric acid vapor to particle growth rate ) ranged from 9.2 to 52.5 % with an average of 26 %. Measurement-based calculated oxidation rates of monoterpenes (i.e. α-pinene, β-pinene, myrcene and limonene) by O 3 positively correlated with the GR 5.5−25 (R = 0.80, p < 0.05). The observed associations of the estimated formation rate J 5.5 and the growth rate GR 5.5−25 with gaseous sulfuric acid and volatile organic compounds (VOCs) suggested the critical roles of sulfuric acid and biogenic VOCs (e.g. α-pinene and β-pinene) in these NPF events.
Abstract. Volatile organic compounds (VOCs) are key precursors of
photochemical smog. Quantitatively evaluating the contributions of VOC
sources to ozone (O3) formation could provide valuable information for
emissions control and photochemical pollution abatement. This study analyzed
continuous measurements of VOCs during the photochemical season in 2014 at a
receptor site (Heshan site, HS) in the Pearl River Delta (PRD) region, where
photochemical pollution has been a long-standing issue. The averaged mixing
ratio of measured VOCs was 34±3 ppbv, with the largest contribution
from alkanes (17±2 ppbv, 49 %), followed by aromatics, alkenes
and acetylene. The positive matrix factorization (PMF) model was applied to
resolve the anthropogenic sources of VOCs, coupled with a
photochemical-age-based parameterization that better considers the
photochemical processing effects. Four anthropogenic emission sources were
identified and quantified, with gasoline vehicular emission as the most
significant contributor to the observed VOCs, followed by diesel vehicular
emissions, biomass burning and solvent usage. The O3 photochemical
formation regime at the HS was identified as VOC-limited by a photochemical
box model with the master chemical mechanism (PBM-MCM). The PBM-MCM model
results also suggested that vehicular emission was the most important source
to the O3 formation, followed by biomass burning and solvent usage.
Sensitivity analysis indicated that combined VOC and NOx emission
controls would effectively reduce incremental O3 formation when the
ratios of VOC-to-NOx emission reductions were > 3.8 for
diesel vehicular emission, > 4.6 for solvent usage, > 4.6 for biomass burning and 3.3 for gasoline vehicular emission. Based on
the above results, a brief review of the policies regarding the control of
vehicular emissions and biomass burning in the PRD region from a regional
perspective were also provided in this study. It reveals that different
policies have been, and continue to be, implemented and formulated and could help
to alleviate the photochemical pollution in the PRD region. Nevertheless,
evaluation of the cost-benefit of each policy is still needed to improve air
quality.
Ozone (O3), a main component in photochemical smog, is a secondary pollutant formed through complex photochemical reactions involving nitrogen oxides (NOx) and volatile organic compounds (VOCs).
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