Mid-infrared laser absorption spectroscopy utilizing a high-finesse optical cavity enables high precision trace analysis of gas molecules. In particular, optical detection of radiocarbon (14C) based on cavity ringdown spectroscopy using a quantum cascade laser (QCL) is gaining attention as an alternative to accelerator mass spectrometry. This paper reports a compact-packaged narrow-linewidth QCL system utilizing resonant optical feedback from an external V-shaped cavity. Based on frequency noise analysis, the derived laser linewidth is 44 kHz for 100 μs integration time with the capability to perform seamless frequency scanning around 10 GHz. We installed this laser system within a table-top cavity ringdown spectrometer for 14CO2. A single-shot detection limit of 1.2 × 10−9 cm−1 Hz−1/2 leading to a detectable abundance evaluated from a noise analysis of 0.2 in fraction modern 14C for a 10-s averaging time was achieved. This capability of rapid analysis for 14CO2 is suitable for various applications requiring trace 14C analysis.
We numerically performed wave dynamical simulations based on the Maxwell-Bloch (MB) model for a quadrupole-deformed microcavity laser with spatially selective pumping. We demonstrate the appearance of an asymmetric lasing mode whose spatial pattern violates both the x-and y-axes mirror symmetries of the cavity. Dynamical simulations revealed that a lasing mode consisting of a clockwise or counterclockwise rotating-wave component is a stable stationary solution of the MB model. From the results of a passive-cavity mode analysis, we interpret these asymmetric rotatingwave lasing modes by the locking of four nearly degenerate passive-cavity modes. For comparison, we carried out simulations for a uniform pumping case and found a different locking rule for the nearly degenerate modes. Our results demonstrate a nonlinear dynamical mechanism for the formation of a lasing mode that adjusts its pattern to a pumped area.
By numerical simulations and experiments of fully chaotic billiard lasers, we show that single-mode lasing states are stable, whereas multi-mode lasing states are unstable when the size of the billiard is much larger than the wavelength and the external pumping power is sufficiently large. On the other hand, for integrable billiard lasers, it is shown that multi-mode lasing states are stable, whereas single-mode lasing states are unstable. These phenomena arise from the combination of two different nonlinear effects of mode-interaction due to the active lasing medium and deformation of the billiard shape. Investigations of billiard lasers with various shapes revealed that single-mode lasing is a universal phenomenon for fully chaotic billiard lasers.
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