Due to its excellent flexibility, graphene has an important application prospect in epidermal electronic sensors. However, there are drawbacks in current devices, such as sensitivity, range, lamination, and artistry. In this work, we have demonstrated a multilayer graphene epidermal electronic skin based on laser scribing graphene, whose patterns are programmable. A process has been developed to remove the unreduced graphene oxide. This method makes the epidermal electronic skin not only transferable to butterflies, human bodies, and any other objects inseparably and elegantly, merely with the assistance of water, but also have better sensitivity and stability. Therefore, pattern electronic skin could attach to every object like artwork. When packed in Ecoflex, electronic skin exhibits excellent performance, including ultrahigh sensitivity (gauge factor up to 673), large strain range (as high as 10%), and long-term stability. Therefore, many subtle physiological signals can be detected based on epidermal electronic skin with a single graphene line. Electronic skin with multiple graphene lines is employed to detect large-range human motion. To provide a deeper understanding of the resistance variation mechanism, a physical model is established to explain the relationship between the crack directions and electrical characteristics. These results show that graphene epidermal electronic skin has huge potential in health care and intelligent systems.

Most mute people cannot speak due to their vocal cord lesion. Herein, to assist mute people to “speak”, we proposed a wearable skinlike ultrasensitive artificial graphene throat (WAGT) that integrated both sound/motion detection and sound emission in single device. In this work, the growth and patterning of graphene can be realized at the same time, and a thin poly­(vinyl alcohol) film with laser-scribed graphene was obtained by a water-assisted transferring process. In virtue of the skinlike and low-resistant substrate, the WAGT has a high detection sensitivity (relative resistance changes up to 150% at 133 Ω) and an excellent sound-emitting ability (up to 75 dB at 0.38 W power and 2 mm distance). On the basis of the excellent mechanical-electrical performance of graphene structure, the sound detecting and emitting mechanisms of WAGT are realized and discussed. For sound detection, both the motion of larynx and vibration of vocal cord contribute to throat movements. For sound emission, a thermal acoustic model for WAGT was established to reveal the principle of sound emitting. More importantly, a homemade circuit board was fabricated to build a dual-mode system, combining the detection and emitting systems. Meanwhile, different human motions, such as strong and small throat movements, were also detected and transformed into different sounds like “OK” and “NO”. Therefore, the implementation of these sound/motion detection acoustic systems enable graphene to achieve device-level applications to system-level applications, and those graphene acoustic systems are wearable for its miniaturization and light weight.

A copper-catalyzed system has been introduced for the enantioselective defluoroalkylation of linear 1-(trifluoromethyl)alkenes through C-F activation to synthesize various gem-difluoroalkenes as carbonyl mimics. For the first time, arylboronate-activated alkyl Grignard reagents were uncovered in this cross-coupling reaction. Mechanistic studies confirmed that the tetraorganoborate complexes generated in situ were the key reactive species for this transformation.