Interface engineering is one feasible and effective approach to minimize the interfacial nonradiative recombination stemming from interfacial defects, interfacial residual stress, and interfacial energy level mismatch. Herein, a novel and effective steric-hindrance-dependent buried interface defect passivation and stress release strategy is reported, which is implemented by adopting a series of adamantane derivative molecules functionalized with CO (i.e., 2-adamantanone (AD), 1-adamantane carboxylic acid (ADCA), and 1-adamantaneacetic acid (ADAA)) to modify SnO 2 /perovskite interface. All modifiers play a role in passivating interfacial defects, mitigating interfacial strain, and enhancing device performance. The steric hindrance of chemical interaction between CO in these molecules and perovskites as well as SnO 2 is determined by the distance between CO and bulky adamantane ring, which gradually decreases from AD, ADCA, and ADAA. The experimental and theoretical evidences together confirmed steric-hindrance-dependent defect passivation effect and interfacial chemical interaction strength. The interfacial chemical interaction strength, defect passivation effect, stress release effect and thus device performance are negatively correlated with steric hindrance. Consequently, the ADAA-modified device achieves a seductive efficiency up to 23.18%. The unencapsulated devices with ADAA maintain 81% of its initial efficiency after aging at 60 °C for 1000 h.
commercial polyimide (PI) films with infrared lasers in a protective atmosphere; while subsequent studies showed that LIG can also be processed with a variety of lasers, including infrared and ultraviolet lasers, [6,7] and using both synthetic materials and natural materials (e.g., cork and fruit shells [1,8] ) as the precursor of graphene. The microscopic mechanisms governing the LIG process have been investigated in recent years through reactive molecular dynamics models, [7,9,10] providing a theoretical base for understanding the graphene formation process during LIG.Various applications of LIG have been demonstrated, including supercapacitor, [11] gas sensor, [12] Joule heater, [13,14] and solid-state triboelectric nanogenerator (TENG). [15][16][17] Among these devices, TENG, which exploits the coupling effect of triboelectricity and electrostatic induction [18][19][20] to generate energy, has found applications in many areas. The device can not only collect small-scale environmental mechanical energy, such as kinetic energy of human movement, [21,22] mechanical vibration energy, [23][24][25][26] rotational kinetic energy, [27,28] wind energy, [29][30][31] etc., but also be used as a self-powered sensor for monitoring mechanical motion. [32,33] Laser-induced graphene (LIG) has emerged as a promising and versatile method for high-throughput graphene patterning; however, its full potential in creating complex structures and devices for practical applications is yet to be explored. In this study, an in-situ growing LIG process that enables to pattern superhydrophobic fluorine-doped graphene on fluorinated ethylene propylene (FEP)-coated polyimide (PI) is demonstrated. This method leverages on distinct spectral responses of FEP and PI during laser excitation to generate the environment preferentially for LIG formation, eliminating the need for multistep processes and specific atmospheres. The structured and water-repellant structures rendered by the spectral-tuned interfacial LIG process are suitable as the electrode for the construction of a flexible dropletbased electricity generator (DEG), which exhibits high power conversion efficiency, generating a peak power density of 47.5 W m −2 from the impact of a water droplet 105 µL from a height of 25 cm. Importantly, the device exhibits superior cyclability and operational stability under high humidity and various pH conditions. The facile process developed can be extended to realize various functional devices.The ORCID identification number(s) for the author(s) of this article can be found under https://doi.org/10.1002/adma.202104290.
It is a challenge for any optical method to measure objects with a large range of reflectivity variation across the surface. Image saturation results in incorrect intensities in captured fringe pattern images, leading to phase and measurement errors. This paper presents a new adaptive digital fringe projection technique which avoids image saturation and has a high signal to noise ratio (SNR) in the three-dimensional (3-D) shape measurement of objects that has a large range of reflectivity variation across the surface. Compared to previous high dynamic range 3-D scan methods using many exposures and fringe pattern projections, which consumes a lot of time, the proposed technique uses only two preliminary steps of fringe pattern projection and image capture to generate the adapted fringe patterns, by adaptively adjusting the pixel-wise intensity of the projected fringe patterns based on the saturated pixels in the captured images of the surface being measured. For the bright regions due to high surface reflectivity and high illumination by the ambient light and surfaces interreflections, the projected intensity is reduced just to be low enough to avoid image saturation. Simultaneously, the maximum intensity of 255 is used for those dark regions with low surface reflectivity to maintain high SNR. Our experiments demonstrate that the proposed technique can achieve higher 3-D measurement accuracy across a surface with a large range of reflectivity variation.
While a few proposed control strategies have shown their acceptable effectiveness, performance improvement on stability and robustness of unmanned helicopters are still imperative and a great challenge due to strong nonlinearities, extensive parameter uncertainties and external disturbances when the flight condition is terrible, such as flight on a windy day. Because acceleration feedback control is advantageous in terms of simple controller structure and easy implementation, we attempt to incorporate it into the tracking control of an unmanned helicopter that is highly nonlinear and underactuated. In this paper, we use a prefilter to formulate a new acceleration feedback control and then use it as a robust enhancement for the H 1 algorithm to attenuate uncertainties and external disturbances involved in the tracking control of an unmanned helicopter. We conduct simulations with an unmanned model helicopter and compare the tracking performance of the helicopter with and without acceleration feedback control. The results show that the use of acceleration feedback control does enhance tracking performance greatly compared to the standard H 1 control.
In the last decade, a significant number of techniques for three-dimensional (3D) shape measurement have been proposed. There are a large number of measurement demands for metallic workpieces with shiny surfaces in industrial applications; however, such shiny surfaces cannot be directly measured using the conventional structured light method. Therefore, various techniques have been investigated to solve this problem over the last few years. Some reviews summarize the different 3D imaging techniques; however, no comprehensive review exists that provides an insight into high-dynamic range (HDR) 3D shape measurement techniques used for shiny surfaces. We present a survey of recent HDR techniques for the digitization of shiny surfaces and classify and discuss the advantages and drawbacks of different techniques with respect to each other.
We report rapid and high-resolution tomographic en face imaging of human liver specimens by full-field optical coherence tomography (FF-OCT). First, the arrangement of the FF-OCT system was described and the performance of the system was measured. The measured axial and lateral resolutions of the system are 0.8 and 0.9 μm, respectively. The system has a sensitivity of ∼60 dB and can achieve an imaging rate of 7 fps and a penetration depth of ∼80 μm. The histological structures of normal liver can be seen clearly in the en face tomographic images, including central veins, cords of hepatocytes separated by sinusoidal spaces, and portal area (portal vein, the hepatic arteriole, and the bile duct). A wide variety of histological subtypes of hepatocellular carcinoma was observed in en face tomographic images, revealing notable cancerous features, including the nuclear atypia (enlarged convoluted nuclei), the polygonal tumor cells with obvious resemblance to hepatocytes with enlarged nuclei. In addition, thicker fibrous bands, which make the cytoplasmic plump vesicular nuclei indistinct, were also seen in the images. Finally, comparison between the portal vein in a normal specimen versus that seen in the rare type of cholangiocarcinoma was made. The results show that the cholangiocarcinoma presents with a blurred pattern of portal vein in the lateral direction and an aggregated distribution in the axial direction; the surrounding sinusoidal spaces and nuclei of cholangiocarcinoma are absent. The findings in this work may be used as additional signs of liver cancer or cholangiocarcinoma, demonstrating capacity of FFOCT device for early cancer diagnosis and many other tumor-related studies in biopsy.
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