In this paper, we report the safe removal of methyl orange (MO) dye from aqueous solution using chemical interaction of dye molecule with polyaniline/zinc oxide (PANI/ZnO) nanocomposite. PANI/ZnO nanocomposite has been prepared by in situ polymerization. PANI/ZnO nanocomposite was found to be the best promising candidate for adsorption of dyes due to more porosities compared to that of pure PANI. In the present investigation, PANI/ZnO nanocomposite was mixed in a solution of MO dye and used for adsorption process. Color removal was studied using UV-Vis spectroscopy and the spectra were recorded for specific time interval and validation of kinetic model has been applied. Absorbance of PANI/ZnO nanocomposite was found to be increased as compared to that of pure ZnO nanoparticles and pure PANI due to synergistic effect. Comparatively, the removal of dye was also found to be more by using PANI/ZnO nanocomposites. In order to evaluate kinetic mechanism the pseudo-first-order model, pseudo-second-order model and intraparticle diffusion models were verified by the linear equation analysis. Adsorption mechanism of pseudo-second-order model was systematically explained for removal of dye using PANI/ZnO nanocomposite. The results clearly demonstrated that the adsorption mechanism gives very novel and green method of removal of hazardous dyes from waste water.
A titanium-substituted hydroxyapatite has been prepared using titanium (IV) isopropoxide as a titanium source to obtain a biomaterial having an improved biocompatibility. From the XRD analysis, it was confirmed that the single-phase hydroxyapatite containing titanium has formed without revealing the presence of extra phases related to titanium dioxide or other calcium phosphate species. Titanium content was up to 0.73% by weight. EDS investigation confirmed the presence of titanium in the framework of hydroxyapatite structure.
The purpose of this study is to determine the correct estimation of the mechanical property between epoxy resin and PEEK sheet as the composites and its validity has been tested with the alternative materials of the metal-based materials for artificial hip joint. Moreover, this work evaluated the mechanical properties according to the temperature of heat treatments for sizing removal of carbon fiber and the fractured surfaces of Carbon/Epoxy and Carbon/PEEK composites were also evaluated. First, the sizing removal of carbon fiber were conducted at 300°C for 4 hours and 400°C for 2 hours. The fractured surface in the specimen of tensile test made from PEEK and epoxy resin was observed by SEM. the fracture surface of the tensile test specimen of the Carbon/Epoxy composites heat-treated to 400°C showed that the resin did not bury nearly in the fiber surface and pull out was observed. It is shown that 400°C is suitable for the sizing removal of the carbon fiber. The mechanical test result showed that there was no significant differences in short beam strength. However, the tensile strength and compressive strength of the Carbon/PEEK composites was higher than those of the Carbon/Epoxy composites in the case of the Vacuum Bag process. In addition, this result showed that the sizing material did not have a significant effect on the strength of the Carbon/PEEK composites.
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