Carbon allotropes are subject of intense investigations for their superb structural, electronic, and chemical properties, but not for topological band properties because of the lack of strong spin-orbit coupling (SOC). Here, we show that conjugated p-orbital interactions, common to most carbon allotropes, can in principle produce a new type of topological band structure, forming the so-called Weyl-like semimetal in the absence of SOC. Taking a structurally stable interpenetrated graphene network (IGN) as example, we show, by first-principles calculations and tight-binding modeling, that its Fermi surface is made of two symmetry-protected Weyl-like loops with linear dispersion along perpendicular directions. These loops are reduced to Weyl-like points upon breaking of the inversion symmetry. Because of the topological properties of these band-structure anomalies, remarkably, at a surface terminated by vacuum there emerges a flat band in the loop case and two Fermi arcs in the point case. These topological carbon materials may also find applications in the fields of catalysts.
We report the design, simulation, and measurement of a dual-band metamaterial absorber in the terahertz region. Theoretical and experimental results show that the absorber has two distinct and strong absorption points near 0.45 and 0.92 THz, both which are related to the LC resonance of the metamaterial. The distributions of the power flow and the power loss indicate that the absorber is an excellent electromagnetic wave collector: the wave is first trapped and reinforced in certain specific locations and then completely consumed. This dual-band absorber has applications in many scientific and technological areas.
Membranes are recognized as a key component in many environment and energy-related applications, but conventional membranes are challenged to satisfy the growing demand for ever more energy-efficient processes. Janus membranes, a novel class with asymmetric properties on each side, have recently emerged and represent enticing opportunities to address this challenge. With an inner driving force arising from their asymmetric configuration, Janus membranes are appealing for enhancing energy efficiency in a variety of membrane processes by promoting the desired transport. Here, the fundamental principles to prepare Janus membranes with asymmetric surface wettability and charges are summarized, and how they work in conventional and unconventional membrane processes is demonstrated.
Wearable health monitoring systems have gained considerable interest in recent years owing to their tremendous promise for personal portable health watching and remote medical practices. The sensors with excellent flexibility and stretchability are crucial components that can provide health monitoring systems with the capability of continuously tracking physiological signals of human body without conspicuous uncomfortableness and invasiveness. The signals acquired by these sensors, such as body motion, heart rate, breath, skin temperature and metabolism parameter, are closely associated with personal health conditions. This review attempts to summarize the recent progress in flexible and stretchable sensors, concerning the detected health indicators, sensing mechanisms, functional materials, fabrication strategies, basic and desired features. The potential challenges and future perspectives of wearable health monitoring system are also briefly discussed.
Graphene as a two-dimensional (2D) topological Dirac semimetal has attracted much attention for its outstanding properties and potential applications. However, three-dimensional (3D) topological semimetals for carbon materials are still rare. Searching for such materials with salient physics has become a new direction for carbon research. Here, using first-principles calculations and tight-binding modeling, we study three types of 3D graphene networks whose properties inherit those of Dirac electrons in graphene. In the band structures of these materials, two flat Weyl surfaces appear in the Brillouin zone (BZ), which straddle the Fermi level and are robust against external strain. When the networks are cut, the resulting lower-dimensional slabs and nanowires remain to be semimetallic with Weyl line-like and point-like Fermi surfaces, respectively. Between the Weyl lines, flat surface bands emerge with strong magnetism when each surface carbon atom is passivated by one hydrogen atom. The robustness of these structures can be traced back to a bulk topological invariant, ensured by the sublattice symmetry, and to the one-dimensional (1D) Weyl semimetal behavior of the zigzag carbon chain, which has been the common backbone to all these structures. The flat Weyl-surface semimetals may enable applications in correlated electronics, as well as in energy storage, molecular sieve, and catalysis because of their good stability, porous geometry, and large superficial area.2
An active terahertz (THz) metamaterial with vanadium dioxide (VO2) cut-wire resonators fabricated on glass substrate was proposed, and THz time-domain spectroscopy was used to probe the temperature-tuned electromagnetic properties. By thermal-triggering the insulator-metal phase transition of VO2, THz transmission signals through the metamaterial exhibit a significant decline with amplitude over 65%. Numerical simulations confirm the observations are due to the metallization of the VO2 film with increasing temperature.
The thermoelectric properties of hybrid graphene/boron nitride nanoribbons (BCNNRs) are investigated using the nonequilibrium Green's function approach. We find that the thermoelectric figure of merit (ZT ) can be remarkably enhanced by periodically embedding hexagonal BN (h-BN) into graphene nanoribbons (GNRs). Compared to pristine GNRs, the ZT for armchair-edged BCNNRs with width index 3p + 2 is enhanced 10-20 times, while the ZT of nanoribbons with other widths is enhanced by just 1.5-3 times. As for zigzag-edge nanoribbons, the ZT is enhanced 2-3 times. This improvement comes from the combined increase in the Seebeck coefficient and the reduction in the thermal conductance outweighing the decrease in the electrical conductance. In addition, the effect of the component ratio of h-BN on the thermoelectric transport properties is discussed. These results qualify BCNNRs as a promising candidate for building outstanding thermoelectric devices.
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