The review summarizes the recent progress in the synthesis, fundamental properties, morphology, photocatalytic applications and challenges of CdS-based photocatalysts.

The spin-orbital interaction in heavy nonmagnetic metal/ferromagnetic metal bilayer systems has attracted great attention and exhibited promising potentials in magnetic logic devices, where the magnetization direction is controlled by passing an electric current. It is found that the spin-orbital interaction induces both an effective field and torque on the magnetization, which have been attributed to two different origins: the Rashba effect and the spin Hall effect. It requires quantitative analysis to distinguish the two mechanisms. Here we show sensitive spin-orbital effective field measurements up to 10 nm thick ferromagnetic layer and find the effective field rapidly diminishes with the increase of the ferromagnetic layer thickness. We further show that this effective field persists even with the insertion of a copper spacer. The nonlocal measurement suggests that the spin-orbital effective field does not rely on the heavy normal metal/ferromagnetic metal interface.

We report the design, simulation, and measurement of a dual-band metamaterial absorber in the terahertz region. Theoretical and experimental results show that the absorber has two distinct and strong absorption points near 0.45 and 0.92 THz, both which are related to the LC resonance of the metamaterial. The distributions of the power flow and the power loss indicate that the absorber is an excellent electromagnetic wave collector: the wave is first trapped and reinforced in certain specific locations and then completely consumed. This dual-band absorber has applications in many scientific and technological areas.

Endured, low‐cost, and high‐performance flexible perovskite solar cells (PSCs) featuring lightweight and mechanical flexibility have attracted tremendous attention for portable power source applications. However, flexible PSCs typically use expensive and fragile indium–tin oxide as transparent anode and high‐vacuum processed noble metal as cathode, resulting in dramatic performance degradation after continuous bending or thermal stress. Here, all‐carbon‐electrode‐based flexible PSCs are fabricated employing graphene as transparent anode and carbon nanotubes as cathode. All‐carbon‐electrode‐based flexible devices with and without spiro‐OMeTAD (2,2′,7,7′‐tetrakis‐(N,N‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene) hole conductor achieve power conversion efficiencies (PCEs) of 11.9% and 8.4%, respectively. The flexible carbon‐electrode‐based solar cells demonstrate superior robustness against mechanical deformation in comparison with their counterparts fabricated on flexible indium–tin oxide substrates. Moreover, all carbon‐electrode‐based flexible PSCs also show significantly enhanced stability compared to the flexible devices with gold and silver cathodes under continuous light soaking or 60 °C thermal stress in air, retaining over 90% of their original PCEs after 1000 h. The promising durability and stability highlight that flexible PSCs are fully compatible with carbon materials and pave the way toward the realization of rollable and low‐cost flexible perovskite photovoltaic devices.

An active terahertz (THz) metamaterial with vanadium dioxide (VO2) cut-wire resonators fabricated on glass substrate was proposed, and THz time-domain spectroscopy was used to probe the temperature-tuned electromagnetic properties. By thermal-triggering the insulator-metal phase transition of VO2, THz transmission signals through the metamaterial exhibit a significant decline with amplitude over 65%. Numerical simulations confirm the observations are due to the metallization of the VO2 film with increasing temperature.

An electronic skin (e-skin) that can detect both normal and tangential forces with a differentiable signals output is essential for wearable electronics. A flexible, stretchable, and highly sensitive tactile sensor is presented that enables the detection of both normal and tangential forces, with specific opposite and thus easily being differentiated resistance changing outputs. The e-skin, which is based on two-sublayered carbon nanotubes (CNTs)/ graphene oxide (GO) hybrid 3D conductive networks, that are anchored on a thin porous polydimethylsiloxane (PDMS) layer, is synthesized via a porogen (GO wrapped NaCl) assisted self-assembling process. The fabricated CNTs/ GO@PDMS-based e-skin shows superior sensitivity (gauge factor of 2.26 under a pressure loading of 1 kPa) to tangential force, moderate sensitivity (−0.31 kPa −1 at 0.05-3.8 kPa, and −0.03 kPa −1 at 3.8-6.3 kPa, respectively) to normal force, and a high-reproducible response over 5000 loading cycles including stretching, bending, and shearing. For applications, the e-skin can not only detect wrist pulsing, discriminating different roughness of surfaces, but also produce an obvious responding to an extremely slight ticking (<20 mg) from a feather, and even can real-timely monitor human's breath and music in rhythm.

The exploration of advanced and novel photocatalytic materials has been widely investigated in recent years. MXene, a new two-dimensional (2D) transition metal material, is gaining attention as a suitable alternative for promoting photocatalytic performance because of its flexible adjustability of elemental composition, regular layered structure, and excellent electrical conductivity. This Perspective summarizes the recent significant advancements in 2D MXene-based photocatalysts for solar fuel conversion. The rational design and specific effects of MXene-based photocatalysts for photocatalytic solar fuel generation are described. Moreover, the different roles of MXene in MXene-based photocatalysts, such as functional group provider, photocatalytic electronic acceptor, substrate, and cocatalyst, for improving photocatalytic performance are discussed. Further discussion about the challenges and optimizations for improvements of 2D MXene and MXene-based photocatalysts in the context of promising solar fuel generation is also presented.

This review summarizes the development of PCN, i.e., synthesis, morphology, modification, and application in recent years. This review can provide a comprehensive view of PCN and lay a foundation for the design of ideal photocatalysts in the future.