Rechargeable batteries have been used to power various electric devices and store energy from renewables, but their toxic components (namely, electrode materials, electrolyte, and separator) generally cause serious environment issues when disused. Such toxicity characteristic makes them difficult to power future wearable electronic devices. Now an environmentally friendly and highly safe rechargeable battery, based on a pyrene-4,5,9,10-tetraone (PTO) cathode and zinc anode in mild aqueous electrolyte is presented. The PTO-cathode shows a high specific capacity (336 mAh g ) for Zn storage with fast kinetics and high reversibility. Thus, the PTO//Zn full cell exhibits a high energy density (186.7 Wh kg ), supercapacitor-like power behavior and long-term lifespan (over 1000 cycles). Moreover, a belt-shaped PTO//Zn battery with robust mechanical durability and remarkable flexibility is first fabricated to clarify its potential application in wearable electronic devices.
A low-cost CoMoP@C electrocatalyst exhibits high efficiency and stable HER performance superior to commercial 20% Pt/C, and can directly work in seawater for the HER with a Faradaic efficiency of 92.5%.
Given the low cost, ease of fabrication, high safety, and environmental‐friendly characteristics, aqueous rechargeable batteries using mild aqueous solutions as electrolytes (pH is close to 7) and a monovalent/multivalent metal ion as charge carrier, are attracting extensive attention for energy storage. However, accompanied by advantages of mild aqueous electrolyte mentioned above, there are some challenges that stand in the way of the development of these aqueous rechargeable batteries, such as the narrow stable electrochemical window of water, instability of electrode materials, undesired side reactions, etc. In recent years, a massive effort is devoted to overcoming the drawbacks, and some encouraging works have arisen. In this review, the latest advances of electrolyte and electrode materials in aqueous batteries based on monovalent ion (Li+, Na+, K+) and multivalent ion (Zn2+, Mg2+, Ca2+, Al3+) are briefly reviewed.
Exploration
of cheap, efficient, and highly durable transition-metal-based
electrocatalysts is critically important for the renewable energy
chain, including both energy storage and energy conversion. Herein,
we have developed cobalt (Co) single atoms anchored in porous nitrogen-doped
carbon nanoflake arrays, synthesized from Co-MOF precursor and followed
by removal of the unwanted Co clusters. The well-dispersed Co single
atoms are attached to the carbon network through N–Co bonding,
where there is extra porosity and active surface area created by the
removal of the Co metal clusters. Interestingly, compared with those
electrocatalysts containing excess Co nanoparticles, a single Co atom
alone demonstrates a lower oxygen evolution reaction (OER) overpotential
and much higher oxygen reduction reaction (ORR) saturation current,
showing that the Co metal clusters are redundant in driving both OER
and ORR. Given the bifunctional electrocatalytic activity and mechanical
flexibility, the electrocatalyst assembled on carbon cloth is employed
as the air cathode in a solid-state Zn–air battery, which presents
good cycling stabilities (2500 min, 125 cycles) as well as a high
open circuit potential (1.411 V).
Abstract. PM2.5 filter samples have been collected in three megacities at the middle and lower reaches of the Yangtze River: Wuhan (WH), Nanjing (NJ), and Shanghai (SH). The samples were analyzed using ultra-high-performance liquid chromatography (UHPLC) coupled with Orbitrap mass spectrometry (MS), which allowed for detection of about 200 formulas of particulate organosulfates (OSs), including dozens of formulas of nitrooxy-organosulfates, with various numbers of isomers for each tentatively determined formula at each location. The number of aliphatic OS formulas represented more than 78 % of the detected OSs at the three locations, while aromatic OSs were much less numerous. OSs with two to four isomers accounted for about 50 % of the total OSs on average in these megacity samples, and the percentage of OSs with six and more isomers in the WH sample was more significant than those in the SH and NJ samples. Additionally, the molecular formula, average molecular weight, and degrees of oxidation and unsaturation of tentatively assigned OSs were compared. The results indicate that the OSs between NJ and SH shared higher similarity, and the characteristics of OSs in SH varied diurnally and seasonally. OSs derived from isoprene, monoterpenes, and sesquiterpenes were abundant in samples from the three megacities and could be produced through both daytime photochemistry and NO3 night-time chemistry. The reaction pathways leading to isoprene-derived OSs probably varied in those locations because of the different NOx levels. In addition, a number of OSs that might be formed from polycyclic aromatic hydrocarbons were also detected, which underlies the importance of anthropogenic sources for this class of compounds.
A multi-interfacial Ni/WC@NC electrocatalyst exhibits highly efficient HER performance over a wide pH range via synergistic electron and mass transfer processes.
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