The oxygen reduction reaction (ORR)
is an important electrode reaction
for energy storage and conversion devices based on oxygen electrocatalysis.
This paper introduces the thermodynamics, reaction kinetics, reaction
mechanisms, and reaction pathways of ORR in aqueous alkaline media.
Recent advances of the catalysts for ORR were extensively reviewed,
including precious metals, nonmetal-doped carbon, carbon–transition
metal hybrids, transition metal oxides with spinel and perovskite
structures, and so forth. The applications of those ORR catalysts
to zinc–air batteries and alkaline fuel cells were briefly
introduced. A concluding remark summarizes the current status of the
reaction pathways, advanced catalysts, and the future challenges of
the research and development of ORR.
Well-separated RGO sheets decorated with MnO2 nanoparticles facilitate easy access of the electrolyte ions to the high surface area of the paper electrode, enabling the fabrication of a thicker electrode with heavier areal mass and higher areal capacitance (up to 897 mF cm(-2) ). The electrochemical performance of the bent asymmetric device with a total active mass of 15 mg remains similar to the one in the flat configuration, demonstrating good mechanical robustness of the device.
In this paper, a very simple solution-based method is employed to coat amorphous MnO2 onto crystalline SnO2 nanowires grown on stainless steel substrate, which utilizes the better electronic conductivity of SnO2 nanowires as the supporting backbone to deposit MnO2 for supercapacitor electrodes. Cyclic voltammetry (CV) and galvanostatic charge/discharge methods have been carried out to study the capacitive properties of the SnO2/MnO2 composites. A specific capacitance (based on MnO2) as high as 637 F g(-1) is obtained at a scan rate of 2 mV s(-1) (800 F g(-1) at a current density of 1 A g(-1)) in 1 M Na2SO4 aqueous solution. The energy density and power density measured at 50 A g(-1) are 35.4 W h kg(-1) and 25 kW kg(-1), respectively, demonstrating the good rate capability. In addition, the SnO2/MnO2 composite electrode shows excellent long-term cyclic stability (less than 1.2% decrease of the specific capacitance is observed after 2000 CV cycles). The temperature-dependent capacitive behavior is also discussed. Such high-performance capacitive behavior indicates that the SnO2/MnO2 composite is a very promising electrode material for fabricating supercapacitors.
Highly active and durable air cathodes to catalyze both the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) are urgently required for rechargeable metal-air batteries. In this work, an efficient bifunctional oxygen catalyst comprising hollow Co O nanospheres embedded in nitrogen-doped carbon nanowall arrays on flexible carbon cloth (NC-Co O /CC) is reported. The hierarchical structure is facilely derived from a metal-organic framework precursor. A carbon onion coating constrains the Kirkendall effect to promote the conversion of the Co nanoparticles into irregular hollow oxide nanospheres with a fine scale nanograin structure, which enables promising catalytic properties toward both OER and ORR. The integrated NC-Co O /CC can be used as an additive-free air cathode for flexible all-solid-state zinc-air batteries, which present high open circuit potential (1.44 V), high capacity (387.2 mAh g , based on the total mass of Zn and catalysts), excellent cycling stability and mechanical flexibility, significantly outperforming Pt- and Ir-based zinc-air batteries.
Exploration
of cheap, efficient, and highly durable transition-metal-based
electrocatalysts is critically important for the renewable energy
chain, including both energy storage and energy conversion. Herein,
we have developed cobalt (Co) single atoms anchored in porous nitrogen-doped
carbon nanoflake arrays, synthesized from Co-MOF precursor and followed
by removal of the unwanted Co clusters. The well-dispersed Co single
atoms are attached to the carbon network through N–Co bonding,
where there is extra porosity and active surface area created by the
removal of the Co metal clusters. Interestingly, compared with those
electrocatalysts containing excess Co nanoparticles, a single Co atom
alone demonstrates a lower oxygen evolution reaction (OER) overpotential
and much higher oxygen reduction reaction (ORR) saturation current,
showing that the Co metal clusters are redundant in driving both OER
and ORR. Given the bifunctional electrocatalytic activity and mechanical
flexibility, the electrocatalyst assembled on carbon cloth is employed
as the air cathode in a solid-state Zn–air battery, which presents
good cycling stabilities (2500 min, 125 cycles) as well as a high
open circuit potential (1.411 V).
Conducting nanowires are of particular interest in energy-related research on devices such as supercapacitors, batteries, water splitting electrodes and solar cells. Their direct electrode/current collector contact and highly conductive 1D structure enable conducting nanowires to provide ultrafast charge transportation. In this paper, we report the facile synthesis of nickel cobalt layered double hydroxides (LDHs) on conducting Zn(2)SnO(4) (ZTO) and the application of this material to a supercapacitor. This study also presents the first report of an enhancement of the active faradic reaction sites (electroactive sites) resulting from the heterostructure. This novel material demonstrates outstanding electrochemical performance with a high specific capacitance of 1805 F g(-1) at 0.5 A g(-1), and an excellent rate performance of 1275 F g(-1) can be achieved at 100 A g(-1). Furthermore, an asymmetric supercapacitor was successfully fabricated using active carbon as a negative electrode. This asymmetric device exhibits a high energy density of 23.7 W h kg(-1) at a power density of 284.2 W kg(-1). Meanwhile, a high power density of 5817.2 W kg(-1) can be achieved at an energy density of 9.7 W h kg(-1). More importantly, this device exhibits long-term cycling stability, with 92.7% capacity retention after 5000 cycles.
Compatible energy storage devices that are able to withstand various mechanical deformations, while delivering their intended functions, are required in wearable technologies. This imposes constraints on the structural designs, materials selection, and miniaturization of the cells. To date, extensive efforts have been dedicated towards developing electrochemical energy storage devices for wearables, with a focus on incorporation of shape-conformable materials into mechanically robust designs that can be worn on the human body. In this review, we highlight the quantified performances of reported wearable electrochemical energy storage devices, as well as their micro-sized counterparts under specific mechanical deformations, which can be used as the benchmark for future studies in this field. A general introduction to the wearable technology, the development of the selection and synthesis of active materials, cell design approaches and device fabrications are discussed. It is followed by challenges and outlook toward the practical use of electrochemical energy storage devices for wearable applications.
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