2D transition metal dichalcogenides are promising candidates for high‐performance photodetectors. However, the relatively low response speed as well as the complex transfer process hinders their wide applications. Herein, for the first time, the fabrication of a few‐layer MoTe2/Si 2D–3D vertical heterojunction for high‐speed and broadband photodiodes by a pulsed laser deposition technique is reported. Owing to the high junction quality, ultrathin MoTe2 film thickness, and unique vertical n–n heterojunction structure, the photodiode exhibits excellent device performance in terms of a high responsivity of 0.19 A W−1 and a large detectivity of 6.8 × 1013 Jones. The device is also capable of detecting a broadband light with wavelength spanning from 300 to 1800 nm. More importantly, the device possesses an ultrahigh response speed up to 150 ns with a 3‐dB electrical bandwidth approaching 0.12 GHz. This work paves the way toward the fabrication of novel 2D–3D heterojunctions for high‐performance, ultrafast photodetectors.
In reflection seismology, full-waveform inversion (FWI) can generate high-wavenumber subsurface velocity models but often suffers from an objective function with local minima caused mainly by the absence of low frequencies in seismograms. These local minima cause cycle skipping when the low-wavenumber component in the initial velocity model for FWI is far from the true model. To avoid cycle skipping, we discovered a new wave-equation reflection traveltime inversion (WERTI) to update the low-wavenumber component of the velocity model, while using FWI to only update high-wavenumber details of the model. We implemented the low- and high-wavenumber inversions in an alternating way. In WERTI, we used dynamic image warping (DIW) to estimate the time shifts between recorded data and synthetic data. When compared with correlation-based techniques often used in traveltime estimation, DIW can avoid cycle skipping and estimate the time shifts accurately, even when shifts vary rapidly. Hence, by minimizing traveltime shifts estimated by dynamic warping, WERTI reduces errors in reflection traveltime inversion. Then, conventional FWI uses the low-wavenumber component estimated by WERTI as a new initial model and thereby refines the model with high-wavenumber details. The alternating combination of WERTI and FWI mitigates the velocity-depth ambiguity and can recover subsurface velocities using only high-frequency reflection data.
Structural design of advanced cathodes is a promising strategy to suppress the shuttle effect for lithium‐sulfur batteries (LSBs). In this work, the carbon cloth covered with CoS2 nanoparticles (CC‐CoS2) is prepared to function as both three‐dimensional (3D) current collector and physicochemical barrier to retard migration of soluble lithium polysulfides. On the one hand, the CC‐CoS2 film works as a robust 3D current collector and host with high conductivity, high sulfur loading, and high capability of capturing polysulfides. On the other hand, the 3D porous CC‐CoS2 film serves as a multifunctional interlayer that exhibits efficient physical blocking, strong chemisorption, and fast catalytic redox reaction kinetics toward soluble polysulfides. Consequently, the Al@S/AB@CC‐CoS2 cell with a sulfur loading of 1.2 mg cm−2 exhibits a high rate capability (≈823 mAh g−1 at 4 C) and delivers excellent capacity retention (a decay of ≈0.021% per cycle for 1000 cycles at 4 C). Moreover, the sandwiched cathode of CC‐CoS2@S/AB@CC‐CoS2 is designed for high sulfur loading LSBs. The CC‐CoS2@S/AB@CC‐CoS2 cells with sulfur loadings of 4.2 and 6.1 mg cm−2 deliver high reversible capacities of 1106 and 885 mAh g−1, respectively, after 100 cycles at 0.2 C. The outstanding electrochemical performance is attributed to the sandwiched structure with active catalytic component.
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