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To extend understanding of the bonding behavior of fiber reinforced polymer (FRP) and steel bars in self-compacting concrete (SCC), an experimental series consisting of 36 direct pull-out tests monitored by acoustic emission (AE) were performed in this paper. The test variables involved rebar type, bar diameter, embedded length, and polypropylene (PP) fiber volume content. For each test, the pull-out force and free end slip were continuously measured and compared with the corresponding AE signals. It was found that the proposed AE method was effective in detecting the debonding process between the FRP/steel bars and the hosting concrete. The AE signal strength exhibited a good correlation with the actual bond stress-slip relationship measured in each specimen. Based on the AE location technique, the invisible non-uniform distribution of bonding stress along the bar was further revealed, the initial location of damage and the debonding process were captured. Additionally, the contribution of bar-to-concrete load-bearing mechanism (chemical adhesion, friction, and mechanical interlocking) to sustain the pull-out force was effectively clarified by studying the collected signals in the frequency domain of AE methods. The experimental results demonstrate that the proposed AE method has potential to detect the debonding damage of FRP/steel bar reinforced SCC structures accurately.

Applying biochar to soil has been proposed as a strategy to enhance soil quality and crop productivity. To further evaluate the influence of biochar and straw application on soil fertility and crop yield, a five-year fixed site field experiment was conducted in a paddy field in Northeast China. The experimental design included six treatments: control (CK), biochar (C), straw (S), chemical fertilizers (NPK), biochar with chemical fertilizer (CNPK) and straw with chemical fertilizer (SNPK). The results showed that compared with the NPK treatment, CNPK and SNPK significantly increased soil total porosity, soil air permeability coefficient, soil organic carbon (SOC), C/N ratio, soil microbial biomass carbon (SMBC)‚ soil microbial biomass nitrogen (SMBN), invertase activity and rice yield. Furthermore, amendment of biochar had a better effect on SOC, C/N ratio, SMBC, and SMBN than that of straw. In addition, SMBC, SOC, and total nitrogen (TN) had significant correlations with soil enzyme activities. Therefore, amendment of biochar with chemical fertilizer is an effective measure to improve rice production and soil quality in the northeast of China.

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This paper investigates the effects of freeze‐thaw (FT) fatigue damage on the cracking behaviors of sandstone specimens containing two unparallel fissures under uniaxial compression. First, the effects of FT fatigue damage and fissure angle on the mechanical properties of sandstone specimens are analyzed. Second, the real‐time cracking process of sandstone specimens is captured by a high‐speed digital video camera system. Seven crack coalescence patterns are observed in this experiment. Local strong fatigue‐damaged zones, which are visualized as white zones, are observed in the specimens subjected to FT cycles during loading. Finally, scanning electron microscopy (SEM) observations show that the local strong fatigue‐damaged zones mainly consisted of microcracks and micropores induced by the FT fatigue damage. These experimental results are helpful for improving the understanding of the cracking process in cold‐region engineering.

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The low-frequency vibrational property of l-phenylalanine (l-Phe) and l-phenylalanine monohydrate (l-Phe·HO) has been investigated by terahertz time-domain spectroscopy (THz-TDS) at room and low temperature ranging from 0.5 to 4.5THz. Distinctive THz absorption spectra of the two compounds were observed. Density functional theory (DFT) calculations based on the crystal structures have been performed to simulate the vibrational modes of l-Phe and l-Phe·HO and the results agree well with the experimental observations. The study indicates that the characterized features of l-Phe mainly originate from the collective vibration of molecules. And the characterized features of l-Phe·HO mainly come from hydrogen bond interactions between l-Phe and water molecules. l-Phe and l-Phe·HO were also verified by differential scanning calorimetry and thermogravimetry (DSC-TG) and powder X-ray diffraction (PXRD) examinations.