Triarylphosphine (I) und Chlormethylisocyanat (II) reagieren zu den monomeren, kristallinen, in Äther unlöslichen Triaryl‐(isocyanatomethyl)‐chlorphosphoranen (III).
Dihalogenphosphite (I) und (V) setzen sich in Gegenwart von Eisen‐ (III)‐chlorid mit Alkylestern der Alkoxy‐chloressigsäure (II) zu Alkylestern der Alkoxy‐(dihalogenphosphonyl)‐essigsäuren (IIIa) und (IIIb) bzw. (VIa) und (VIb) um.
Reaction of Chloroalkylenes with DialkylChloro-and Fluorophosphites. -The β-chlorocrotonate (I) is coupled with the halophosphites (II) to give the halophosphonates (III). -(SHOKOL, V. A.; KOZHUSHKO, B. N.; PALIICHUK, YU. A.; Zh. Obshch. Khim. 60(122) (1990) 7, 1667; Kiev. NII endokrinol. i obmena veshchestv, USSR; RU)
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.