The purpose of this study is to compare the bloating mechanism of artificial lightweight aggregate under sintering and rapid sintering conditions to identify the factors behind the bloating of the lightweight aggregate under these sintering conditions, and to find suitable temperature ramping conditions. The aggregate had an average particle size of 10 mm as formed using acid clay, and it was fired by a rapid sintering method and a normal sintering method. The bulk density and water absorption ratio of the specimen were measured, and the cross section was observed. No black core was observed under the rapid sintering condition, and it was lightened at an inflection point of 1150 °C. A reduction in the bulk density was observed in a shorter period of time when the input temperature was high under the normal sintering conditions. Regardless of the input temperature, the bulk density change was divided into three sections and a bloating-activation zone was observed in which the density abruptly decreased.
A mixed culture utilizing 1,4-dioxane as a sole carbon and energy source was obtained from the activated sludge at a textile wastewater treatment plant. The biodegradation of 1,4-dioxane was characterized by a model based on the Monod equation. The effects of the presence of easily degradable carbon sources other than 1,4-dioxane were investigated using dextrose. Structural analogs commonly found in 1,4-dioxane-containing wastewater such as tetrahydrofuran (THF), 2-methyl-1,3-dioxolane, and 1,4-dioxene were also evaluated for their potential effects on 1,4-dioxane biodegradation. The presence of dextrose did not show any synergetic or antagonistic effects on 1,4-dioxane biodegradation, while the structural analogs showed significant competitive inhibition effects. The inhibitory effects were relatively strong with heptagonal cyclic ethers such as THF and 2-methyl-1,3-dioxolane, and mild with hexagonal cyclic ethers such as 1,4-dioxene. It was also shown that the treatment of 1,4-dioxane in the raw textile wastewater required 170% more time to remove 1,4-dioxane due to the co-presence of 2-methyl-1,3-dioxolane, and the extent of delay depended on the initial concentration of 1,3-doxolane.
In this study, a microbial community of bacteria was investigated for 1,4-dioxane(1,4-D) biodegradation. The enriched culture was investigated for 1,4-dioxane mineralization, co-metabolism of 1,4-dioxane and extra carbon sources, and characterized 1,4-dioxane biodegradation kinetics. The mineralization test indicates that the enriched culture was able to degrade 1,4-dioxane as the sole carbon and energy source. Interestingly, the distribution of 1,4-dioxane into the final biodegrading products were 36.9% into biomass, 58.3% completely mineralized to CO2, and about 4% escaped as VOC. The enriched culture has a high affinity with 1,4-dioxane during biodegradation. The kinetic coefficients of the Monod equation were qmax = 0.0063 mg 1,4-D/mg VSS/h, Ks = 9.42 mg/L, YT = 0.43 mg VSS/mg 1,4-dioxane and the decay rate was kd = 0.023 mg/mg/h. Tetrahydrofuran (THF) and ethylene glycol were both consumed together with 1,4-dioxane by the enriched culture; however, ethylene glycol did not show any influence on 1,4-dioxane biodegradation, while THF proved to be a competitive.
The purpose of this study was to improve the recycling rate of industrial wastes by investigating the bloating mechanism of artificial lightweight aggregate depending on the ramping rate and time, which is a dynamic parameter in the production of artificial lightweight aggregate. In this study, coal bottom ash and dredged soil at a weight ratio of 1 : 1 from a domestic power plant were used as raw materials. The artificial lightweight aggregates were formed by using an extruder and pelletizer (φ = 10 mm) and sintered by rapid sintering, 2-step firing, and normal sintering method. The physical properties of the aggregates such as bulk density, water absorption ratio, and microstructure of cross section are investigated with the sintering time and temperature. As the result of bloating and trapping mechanism, black core could be inhibited as the firing time increased at the temperature before surface formation. As a result of firing schedule graphs using least square method, it was possible to manufacture artificial lightweight aggregate with micropores, specific gravity of 1.1, and absorption rate of 3% at a heating rate of 27°c/min or less.
The chronic ingestion of arsenic (As) contaminated water has raised significant health concerns worldwide. Iron-based coagulants have been widely used to remove As oxyanions from drinking water sources. In addition, the system’s ability to lower As within the maximum acceptable contamination level (MCL) is critical for protecting human health from its detrimental effects. Accordingly, the current study comprehensively investigates the performance of As removal under various influencing factors including pH, contact time, temperature, As (III, V) concentration, ferric chloride (FC) dose, and interfering ions. The optimum pH for As (V) removal with FC was found to be pH 6–7, and it gradually decreased as the pH increased. In contrast, As (III) removal increased with an increase in pH with an optimum pH range of 7–10. The adsorption of As on precipitated iron hydroxide (FHO) was better fitted with pseudo-second order and modified Langmuir–Freundlich models. The antagonistic effect of temperature on As removal with FC was observed, with optimum temperature of 15–25 °C. After critically evaluating the optimum operating conditions, the uptake indices of both As species were developed to select appropriate an FC dose for achieving the MCL level. The results show that the relationship between residual concentration, FC dose, and adsorption affinity of the system was well represented by uptake indices. The higher FC dose was required for suspensions containing greater concentration of As species to achieve MCL level. The As (V) species with a greater adsorption affinity towards FHO require a relatively smaller FC dose than As (III) ions. Moreover, the significant influence of interfering species on As removal was observed in simulated natural water. The author hopes that this study may help researchers and the drinking water industry to develop uptake indices of other targeted pollutants in achieving MCL level during water treatment operations in order to ensure public health safety.
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