A pressure induced semiconductor-semimetal phase transition on tungsten diselenide has been studied using in situ electrical resistivity measurement and first-principles calculation under high pressure. The experimental results indicate that the phase transition takes place at 38.1 GPa. The first-principles calculations performed by CASTEP code based on the density functional theory illustrate that the indirect band gap of WSe 2 vanishes at 35 GPa, which results in an isostructural phase transition from semiconductor to semimetal in WSe 2 . According to the pressure dependence of partial density of states, the semimetallic character of WSe 2 is mainly caused by W-Se covalent bonding rather than van der Waals bonding.
In this work, we report the pressure-dependent electrical transport and structural properties of SnSe. In our experiments an electronic transition from a semiconducting to semimetallic state was observed at 12.6 GPa, followed by an orthorhombic to monoclinic structural transition. Hall effect measurements indicate that both the carrier concentration and mobility vary abnormally accompanied by the semimetallic electronic transition. First-principles band structure calculations confirm the semiconducting-semimetallic transition, and reveal that the semimetallic character of SnSe can be attributed to the enhanced coupling of Sn-5s, Sn-5p, and Se-3p orbitals under compression that results in the broadening of energy bands and subsequently the closure of the band gap. The pressure modulated variations of electrical transport and structural properties may provide an approach to improving the thermoelectric properties of SnSe.
The high-pressure electrical transport behavior of microcrystalline
tungsten trioxides (WO3) was investigated by direct current
electrical resistivity measurement and alternate current impedance
spectrum techniques in a diamond anvil cell up to 35.5 GPa. Discontinuous
changes of electrical resistivity occurred during the pressure induced
structure phase transitions at 1.8, 21.2, and 30.4 GPa. The irreversible
resistivity reveals that the structure phase transition is not reversible.
In addition, the abnormal changes of bulk resistance and transport
activation energy at about 3 and 10 GPa are related to the isostructural
phase transition reported by previous Raman study. The temperature
induced resistivity change indicates that WO3 is a semiconductor
from ambient pressure to 25.3 GPa.
An unexpected superconductivity enhancement is reported in decompressed In Se . The onset of superconductivity in In Se occurs at 41.3 GPa with a critical temperature (T ) of 3.7 K, peaking at 47.1 GPa. The striking observation shows that this layered chalcogenide remains superconducting in decompression down to 10.7 GPa. More surprisingly, the highest T that occurs at lower decompression pressures is 8.2 K, a twofold increase in the same crystal structure as in compression. It is found that the evolution of T is driven by the pressure-induced R-3m to I-43d structural transition and significant softening of phonons and gentle variation of carrier concentration combined in the pressure quench. The novel decompression-induced superconductivity enhancement implies that it is possible to maintain pressure-induced superconductivity at lower or even ambient pressures with better superconducting performance.
Surveillance video parsing, which segments the video frames into several labels, e.g., face, pants, left-leg, has wide applications [38,9]. However, pixel-wisely annotating all frames is tedious and inefficient. In this paper, we develop a Single frame Video Parsing (SVP) method which requires only one labeled frame per video in training stage. To parse one particular frame, the video segment preceding the frame is jointly considered. SVP (i) roughly parses the frames within the video segment, (ii) estimates the optical flow between frames and (iii) fuses the rough parsing results warped by optical flow to produce the refined parsing result. The three components of SVP, namely frame parsing, optical flow estimation and temporal fusion are integrated in an end-to-end manner. Experimental results on two surveillance video datasets show the superiority of SVP over state-of-the-arts.
We report an anomalous phase transition in compressed In2Se3. The high-pressure studies indicate that In2Se3 transforms to a new isosymmetric R-3m structure at 0.8 GPa whilst the volume collapses by ∼7%. This phase transition involves a pressure-induced interlayer shear glide with respect to one another. Consequently, the outer Se atoms of one sheet locate into the interstitial sites of three Se atoms in the neighboring sheets that are weakly connected by van der Waals interaction. Interestingly, this interlayer shear glide changes the stacking sequence significantly but leaves crystal symmetry unaffected. This study provides an insight to the mechanisms of the intriguing isosymmetric phase transition.
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