2017
DOI: 10.1002/adma.201701983
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Decompression‐Driven Superconductivity Enhancement in In2Se3

Abstract: An unexpected superconductivity enhancement is reported in decompressed In Se . The onset of superconductivity in In Se occurs at 41.3 GPa with a critical temperature (T ) of 3.7 K, peaking at 47.1 GPa. The striking observation shows that this layered chalcogenide remains superconducting in decompression down to 10.7 GPa. More surprisingly, the highest T that occurs at lower decompression pressures is 8.2 K, a twofold increase in the same crystal structure as in compression. It is found that the evolution of T… Show more

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Cited by 41 publications
(35 citation statements)
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“…Interestingly, the superconducting volume fraction is about the same as compression data, however, the T c values are not fully recovered. The different T c between compression and decompression is previously reported in In 2 Se 3 , which is intrinsic, as a result of changes in phonon and variation of carrier concentration combined in the pressure quench [32]. Further measurements are needed to confirm if there is indeed a suppressed T c behavior in Ba(Fe 1−x Co x ) 2 As 2 during decompression, which is beyond the scope of this work.…”
Section: Resultsmentioning
confidence: 60%
“…Interestingly, the superconducting volume fraction is about the same as compression data, however, the T c values are not fully recovered. The different T c between compression and decompression is previously reported in In 2 Se 3 , which is intrinsic, as a result of changes in phonon and variation of carrier concentration combined in the pressure quench [32]. Further measurements are needed to confirm if there is indeed a suppressed T c behavior in Ba(Fe 1−x Co x ) 2 As 2 during decompression, which is beyond the scope of this work.…”
Section: Resultsmentioning
confidence: 60%
“…40 More recently, a HP study has revealed a superconductivity enhancement in α-In2Se3 under compression when it undergoes the transition to the defective cubic Th3P4 structure. 44 Finally, a recent HP study has also reported the transition from γ-In2Se3 to β-In2Se3 under compression. 45 In order to shed light into: i) the nature of the α(R) phase; ii) the existence of an intermediate β´ phase between α and β phases; and iii) the presence of a soft phonon in the β phase, we performed ab initio calculations of In2Se3 with R3m, C2/m and R-3m structures.…”
Section: Introductionmentioning
confidence: 96%
“…[ 26,27 ] Furthermore, superconductivity was reported in β‐In 2 Se 3 under high pressure due to phonon softening. [ 28 ]…”
Section: Introductionmentioning
confidence: 99%