Herein, a supermolecular‐scale cage‐confinement pyrolysis strategy is proposed to build two dielectric electromagnetic wave absorbents, in which MoO2 nanoparticles are sandwiched uniformly between porous carbon shells and reduced graphene oxide (RGO). Both sandwich structures are derived from hybrid hydrogels doped by two different crosslinkers (with/without oxygen bridge), which can precisely confine Mo source (e.g., PMo12). Without adding magnetic components, both absorbents exhibit excellent low frequency absorption performance in combination with electrically tunable ability and enhanced reflection loss value, which is superior over other relative 2D dielectric absorbers and satisfies the requirements of portable electronics. Notably, introducing oxygen bridges in the crosslinker generates a more stable confining configuration, which in turn renders its corresponding derivative exhibiting an extra multifrequency electromagnetic wave absorption trait. The intrinsic electromagnetic wave adjustment mechanism of the ternary hybrid absorbent is also explored. The result reveals that the elevated electromagnetic wave absorbing property is attributed to moderate attenuation constant and glorious impendence matching. The cage‐confinement pyrolysis route to fabricate 2D MoO2‐based dielectric electromagnetic wave absorbents opens a new path for the design of electromagnetic wave absorbents used in multi/low frequency.
A new type of zinc oxide/silicon nanowire (ZnO/SiNW) hybrid is developed for use in an extended-gate field-effect transistor (EGFET) for pH sensors. SiNWs are first formed using the Ag-assisted electroless etching technique and are then covered with ZnO nanostructures through a combination of sol-gel and hydrothermal processes. The ZnO nanostructures were synthesized at 90°C for 3 h using precursor solutions with molar concentrations of 10 mM and 25 mM. The ZnO nanostructures provide a larger surface area than the pristine SiNWs for adsorbing additional H+ and OH− ions, along with increased oxygen-related binding to effectively sense H+ ions in the acid solution region. The 25 mM ZnO/SiNW sensors exhibited higher sensitivity (66 mV/pH) than pristine SiNW sensors (52 mV/pH). This simple and low-cost sensing device can be applied in disposable biosensors.
Glass-fiber felts have emerged as a popular material for noise reduction. This paper investigates the effect of various morphologies (micro-layer, macro-layer and air-layer) of glass-fiber felts on sound insulation. The sound transmission loss is measured by a Brüel & Kjár (B&K) impedance tube. The results show that the sound insulation of glass-fiber felts can be improved by increasing the number of macro-layers. The comparison between the macro- and micro-layer of glass-fiber felts on sound insulation is systematically carried out. Notably, the sound transmission loss of glass-fiber felts with similar areal density and thickness favors macro-layer structures over micro-layer structures. A simple model is established to explain this phenomenon. In addition, the sound transmission loss exhibits period fluctuations due to the presence of the air-layer between glass-fiber felts, which can be theoretically explained by the resonance effect. It is found that sound transmission loss can be improved by increasing the number of air-layers.
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