Different photoluminescence (PL) techniques have been used to study the bluegreen emission from siliceous MCM-41 nanotubes. It was found that the intensity of the blue-green PL is enhanced by rapid thermal annealing (RTA). This enhancement is explained by the generation of twofold-coordinated Si centres and non-bridging oxygen hole centres, in line with the surface properties of MCM-41. On the basis of the analysis of the PL following RTA, polarized PL, and PL excitation, we suggest that the triplet-to-singlet transition of twofoldcoordinated silicon centres is responsible for the blue-green PL in MCM-41 nanotubes.
It has been claimed that the mechanical properties of electrodes in lithium‐ion batteries have a huge impact on their electrochemical performance. This is especially critical for Si‐based electrodes, which suffer from pulverization and formation of an unstable solid–electrolyte interphase during cycling. Herein, thin silicon‐coated nickel silicide nanoparticles grown on a nickel inner core support (designated as Si@NixSi/Ni) as anode material for a Li‐ion battery are reported. The ultrathin nano silicon layer contributes to achieve reasonably high energy density and allows fast Li‐ion diffusion due to its high specific capacity and shortened Li‐ion diffusion length. While the gradiently distributed NixSi layer enables the attainment of superior cycling stability and further enhances the specific capacity, the Ni inner core provides mechanical support to maintain the structural integrity of the nanoparticles during the extended lithiation/delithiation process. The Si@NixSi/Ni core–shell electrode exhibits a charge‐specific capacity of 706.1 mAh g−1 at a current density of 500 mA g−1. This structure also shows a high first‐cycle Coulombic efficiency of 81.5%. Interestingly, the Si@NixSi/Ni core–shell electrode demonstrates a cycle life of over 5000 cycles with capacity retention of 74% at a current density of 500 mA g−1.
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