We report on observations of random lasers with coherent feedback in highly transparent polymer films embedded with silver nanoparticles. The hybrid materials were fabricated via in situ synthesis method, through which silver nanoparticles were precipitated by thermal treatment. Sharp peaks with linewidth ϳ0.5 nm were observed to emerge on the broad emission background when the pump energy reached a threshold, together with unidirectional laser irradiation. Random lasers with coherent feedback induced by silver nanoparticles have been rarely reported, hence, we expect that this work will add an aspect to random lasers by using metal nanostructures to obtain coherent feedback.

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Bistable rotation is realized for a gold-coated Janus colloidal particle in an infrared optical trap. The metal coating on the Janus particles are patterned by sputtering gold on a monolayer of closely packed polystyrene particles. The Janus particle is observed to stably rotate in an optical trap. Both the direction and the rate of rotation can be experimentally controlled. Numerical calculations reveal that the bistable rotation is the result of spontaneous symmetry breaking induced by the uneven curvature of the coating patterns on the Janus sphere. Our results thus provide a simple method to construct large quantities of fully functional rotary motors for nano- or microdevices.

We report on epitaxial growth and magnetic properties of EuTiO 3 thin films with a perovskite structure. Single crystalline EuTiO 3 films with atomically flat surface are grown on ͑001͒ surface of SrTiO 3 by pulsed laser deposition ͑PLD͒ and subsequent annealing in reducing atmosphere. The as-deposited films possess the crystal structure with an elongated c-axis and tend to stabilize ferromagnetically ordered Eu 2+ spins at low temperatures. Postannealing at 1000°C relaxes the out-of-plane lattice strain, and brings about a drastic change in magnetic structure; the annealed film becomes an antiferromagnet below Néel temperature of 5.1 K. The change in magnetic properties accompanied by the modification in lattice constant is discussed.

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A comparative study of the crystal and electronic structure and magnetism of divalent europium perovskite oxides EuMO(3) (M = Ti, Zr, and Hf) has been performed on the basis of both experimental and theoretical approaches playing complementary roles. The compounds were synthesized via solid-state reactions. EuZrO(3) and EuHfO(3) have an orthorhombic structure with a space group Pbnm at room temperature contrary to EuTiO(3), which is cubic at room temperature. The optical band gaps of EuZrO(3) and EuHfO(3) are found to be about 2.4 and 2.7 eV, respectively, much larger than that of EuTiO(3) (0.8 eV). On the other hand, the present compounds exhibit similar magnetic properties characterized by paramagnetic-antiferromagnetic transitions at around 5 K, spin flop at moderate magnetic fields lower than 1 T, and the antiferromagnetic nearest-neighbor and ferromagnetic next-nearest-neighbor exchange interactions. First-principles calculations based on a hybrid Hartree-Fock density functional approach yield lattice constants, band gaps, and magnetic interactions in good agreement with those obtained experimentally. The band gap excitations are assigned to electronic transitions from the Eu 4f to Mnd states for EuMO(3) (M = Ti, Zr, and Hf and n = 3, 4, and 5, respectively).

Ureolytic microbially induced calcium carbonate precipitation (MICP) is a promising green technique for addressing a variety of environmental and architectural concerns. However, the dynamics of MICP especially at the microscopic level remains relatively unexplored. In this work, by applying a bacterial tracking technique, the growth dynamics of micrometer-sized calcium carbonate precipitates induced by Sporosarcina pasteurii were studied at a single-cell resolution. The growth of micrometer-scale precipitates and the occurrence and dissolution of many unstable submicrometer calcium carbonate particles were observed in the precipitation process. More interestingly, we observed that micrometer-sized precipitated crystals did not grow on negatively charged cell surfaces nor on other tested polystyrene microspheres with different negatively charged surface modifications, indicating that a negatively charged surface was not a sufficient property for nucleating the growth of precipitates in the MICP process under the conditions used in this study. Our observations imply that the frequently cited model of bacterial cell surfaces as nucleation sites for precipitates during MICP is oversimplified. In addition, additional growth of calcium carbonates was observed on old precipitates collected from previous runs. The presence of bacterial cells was also shown to affect both morphologies and crystalline structures of precipitates, and both calcite and vaterite precipitates were found when cells physically coexisted with precipitates. This study provides new insights into the regulation of MICP through dynamic control of precipitation.

Considering multi-body systems of monodisperse hard Brownian particles, it remains challenging to predict the forms of order that can emerge in their dense assembled structures. Surprisingly, here, using Monte Carlo simulations, we show that tetratic-ordered phases emerge in a dense two-dimensional system of hard kites that are rotationally asymmetric and have opposite 72° and α ≈ 90° internal angles. We observe a new tetragonal rectangular crystal (TRX) phase possessing (quasi-)long-range fourfold molecular-orientational order. We propose a method based on local polymorphic configurations of neighboring particle pairs (LPC-NPPs) to understand this emergent tetratic order and show that LPC-NPPs can be useful for predicting orientational order in such systems. To examine the dependence of the tetratic order on α, we apply LPC-NPP analysis to other hard kites for 54° ≤ α ≤ 144°. Our work provides insight into the creation of novel ordered materials by rationally designing particle shape based on anticipated LPC-NPPs.