The
concept of mixed 2D/3D heterostructures has emerged as an effective
method for improving the stability of lead halide perovskite solar
cells, which has been, however, rarely reported in lead–tin
(Pb–Sn) mixed perovskite devices. Here, we report a scalable
process for depositing mixed 2D/3D Pb–Sn perovskite solar cells
that deliver remarkably enhanced efficiency and stability compared
to their 3D counterparts. The incorporation of a small amount (3.75%)
of an organic cation 2-(4-fluorophenyl)ethylammonium iodide induces
the growth of highly oriented Pb–Sn perovskite crystals perpendicularly
aligned with the substrate. Moreover, for the first time, phase segregation
is observed in pristine 3D Pb–Sn perovskites, which is suppressed
due to the presence of the 2D perovskites. Accordingly, a high current
density of 28.42 mA cm–2 is obtained due to the
markedly enhanced spectral response and charge extraction. Eventually,
mixed 2D/3D Pb–Sn perovskite devices with a band gap of 1.33
eV yield efficiencies as high as 17.51% and in parallel exhibit good
stability.
Superhydrophobic polymer foams are a good candidate for oil absorption because of their lightweight and tunable porosity and have promising applications in the long-term application of oil−water separation. However, developing a facile and green strategy to fabricate pure polymer foams with superhydrophobicity and eco-friendliness for large-scale oil−water separation remains a challenge. Here, a facile template-free water-assisted thermally impacted phase separation approach combined with skin peeling for the fabrication of superhydrophobic and eco-friendly pure poly(lactic acid) (PLA) foam for oil−water separation is proposed for the first time. The PLA foam with special micro-and nanostructures possesses a water contact angle of 151°, and the maximum saturated adsorption capacity is 31.5 g/g. More importantly, during the continuous oil−water pumping experiment, the foam has an efficiency of 98% and could maintain for more than 15 h, showing a promising prospect for cleaning large-scale oil pollution.
The development of multifunctional and efficient electromagnetic wave absorbing materials is a challenging research hotspot. Here, the magnetized Ni flower/MXene hybrids are successfully assembled on the surface of melamine foam (MF) through electrostatic self-assembly and dip-coating adsorption process, realizing the integration of microwave absorption, infrared stealth, and flame retardant. Remarkably, the Ni/MXene-MF achieves a minimum reflection loss (RLmin) of − 62.7 dB with a corresponding effective absorption bandwidth (EAB) of 6.24 GHz at 2 mm and an EAB of 6.88 GHz at 1.8 mm. Strong electromagnetic wave absorption is attributed to the three-dimensional magnetic/conductive networks, which provided excellent impedance matching, dielectric loss, magnetic loss, interface polarization, and multiple attenuations. In addition, the Ni/MXene-MF endows low density, excellent heat insulation, infrared stealth, and flame-retardant functions. This work provided a new development strategy for the design of multifunctional and efficient electromagnetic wave absorbing materials.
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