Salinity gradient power (SGP) has been identified as a promising renewable energy source. Reverse electrodialysis (RED) and pressure retarded osmosis (PRO) are two membrane-based technologies for SGP harvesting. Developing nanopores and nanofluidic membranes with excellent water and/or ion transport properties for applications in those two membrane-based technologies is considered viable for improving power generation performance. Despite recent efforts to advance power generation by designing a variety of nanopores and nanofluidic membranes to enhance power density, the valid pathways toward large-scale power generation remain uncertain. In this review, we introduce the features of ion and water transport in nanofluidics that are potentially beneficial to power generation. Subsequently, we survey previous efforts on nanofluidic membrane synthesis to obtain high power density. We also discuss how the various membrane properties influence the power density in RED and PRO before moving on to other important aspects of the technologies, i.e., system energy efficiency and membrane fouling. We analyze the importance of system energy efficiency and illustrate how the delicately designed nanofluidic membranes can potentially enhance energy efficiency. Previous studies are reviewed on fabricating antifouling and antimicrobial membrane for power generation, and opportunities are presented that can lead to the design of nanofluidic membranes with superior antifouling properties using various materials. Finally, future research directions are presented on advancing membrane performance and scaling-up the system. We conclude this review by emphasizing the fact that SGP has the potential to become an important renewable energy source and that high-performance nanofluidic membranes can transform SGP harvesting from conceptual to large-scale applications.

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The specific properties of metal-based nanoparticles (NPs) have not only led to rapidly increasing applications in various industrial and commercial products, but also caused environmental concerns due to the inevitable release of NPs and their unpredictable biological/ecological impacts. This review discusses the environmental behavior of metal-based NPs with an in-depth analysis of the mechanisms and kinetics. The focus is on knowledge gaps in the interaction of NPs with aquatic organisms, which can influence the fate, transport and toxicity of NPs in the aquatic environment. Aggregation transforms NPs into micrometer-sized clusters in the aqueous environment, whereas dissolution also alters the size distribution and surface reactivity of metal-based NPs. A unique toxicity mechanism of metal-based NPs is related to the generation of reactive oxygen species (ROS) and the subsequent ROS-induced oxidative stress. Furthermore, aggregation, dissolution and ROS generation could influence each other and also be influenced by many factors, including the sizes, shapes and surface charge of NPs, as well as the pH, ionic strength, natural organic matter and experimental conditions. Bioaccumulation of NPs in single organism species, such as aquatic plants, zooplankton, fish and benthos, is summarized and compared. Moreover, the trophic transfer and/or biomagnification of metal-based NPs in an aquatic ecosystem are discussed. In addition, genetic effects could result from direct or indirect interactions between DNA and NPs. Finally, several challenges facing us are put forward in the review.

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Osmotic power has emerged as one of the promising candidates for clean and renewable energy. However, the advancement of present osmotic power-harvesting technologies, specifically pressure-retarded osmosis (PRO) in this work, is hindered by the unsatisfactory membrane transport properties. Herein, we demonstrate the freestanding transition-metal carbides and graphene oxide hybrid membranes as high-performance PRO membranes. Due to the elimination of internal concentration polarization, the freestanding hybrid membrane can achieve a record-high power density up to approximately 56.4 W m–2 with 2.0 M NaCl as the draw solution and river water (0.017 M) as the feed water at an applied hydraulic pressure difference of 9.66 bar. In addition, the hybrid membranes exhibit enhanced antifouling potential and antibacterial activity. The facile fabrication of the hybrid membranes shed light on a new membrane development platform for the highly anticipated osmotic power-harvesting technologies.

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