In order to prepare bulk C3N4, high-pressure pyrolysis of melamine (C3N6H6) at
different temperatures was carried out. The products were characterized by C, N,
H element analysis, Fourier transform infrared spectroscopy, x-ray photoelectron
spectroscopy, and x-ray diffractometry. The results of the analysis reveal that
graphitic phase C3N4 has been synthesized. It provides a novel route to synthesis
of the theoretical superhard cubic C3N4 and other C3N4 phases from
organic compounds by a high-pressure and high-temperature method.
In this study, {111}-oriented diamond crystals with different nitrogen concentrations were successfully synthesized in a series of experiments at 5.8 GPa pressure and 1380–1400 °C temperature.
Materials combining the hardness and strength of diamond with the higher thermal stability of cubic boron nitride (cBN) have broad potential value in science and engineering. Reacting nanodiamond with cBN at moderate pressures and high temperatures provides a pathway to such materials. Here we report the fabrication of Cx-BN nanocomposites, measuring up to 10 mm in longest dimension, by reacting nanodiamond with pre-synthesized cBN in a large-volume press. The nanocomposites consist of randomly-oriented diamond and cBN domains stitched together by sp3-hybridized C-B and C-N bonds, leading to p-type semiconductivity. Dislocations near the sutures accommodate lattice mismatch between diamond and cBN. Nanotwinning within both diamond and cBN domains further contributes to a bulk hardness ~50% higher than sintered cBN. The nanocomposite of C2-BN exhibits p-type semiconductivity with low activation energy and high thermal stability, making it a functional, ultrahard substance.
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