Novel multifunctional poly(ε-caprolactone)-gelatin encapsulating upconversion core/shell silica nanoparticles (NPs) composite fibers as dual drugs delivery system (DDDS), with indomethacin (IMC) and doxorubicin (DOX) releasing in individual release properties, have been designed and fabricated via electrospinning process. Uniform and monodisperse upconversion (UC) luminescent NaYF4:Yb(3+), Er(3+) nanocrystals (UCNCs) were encapsulated with mesoporous silica shells, resulting in the formation of core/shell structured NaYF4:Yb(3+), Er(3+)@mSiO2 (UCNCs@mSiO2) NPs, which can be performed as DOX delivery carriers. These UCNCs@mSiO2 NPs loading DOX then were dispersed into the mixture of poly(ε-caprolactone) (PCL) and gelatin-based electrospinning solution containing IMC, followed by the preparation of dual drug-loaded composite fibers (DDDS) via electrospinning method. The drugs release profiles of the DDDS were measured, and the results indicated that the IMC and DOX released from the electrospun composite fibers showed distinct properties. The IMC in the composite fibers presented a fast release manner, while DOX showed a sustained release behavior. Moreover, the UC luminescent intensity ratios of (2)H(11/2)/(4)S(3/2)-(4)I(15/2) to (4)F(9/2)-(4)I(15/2) from Er(3+) vary with the amounts of DOX in the system, and thus drug release can be tracked and monitored by the luminescence resonance energy transfer (LRET) mechanism.
In the first part of this work, we analyzed an unconstrained Dirichlet boundary control problem for an elliptic convection diffusion PDE and proposed a new hybridizable discontinuous Galerkin (HDG) method to approximate the solution. For the case of a 2D convex polygonal domain, we also proved an optimal superlinear convergence rate for the control under certain assumptions on the domain and on the target state. In this work, we revisit the convergence analysis without these assumptions; in this case, the solution can have low regularity and we use a different analysis approach. We again prove an optimal convergence rate for the control, and present numerical results to illustrate the convergence theory.
In order to meet the growing need for smart bionic devices and epidermal electronic systems, biaxial stretchability is essential for energy storage units. Based on porous single-walled carbon nanotube/poly(3,4-ethylenedioxythiophene) (SWCNT/PEDOT) hybrid fiber, we designed and fabricated a biaxially stretchable supercapacitor, which possesses a unique configuration of the parallel buckled hybrid fiber array. Owing to the reticulate SWCNT film and the improved fabrication technique, the hybrid fiber retained its porous architecture both outwardly and inwardly, manifesting a superior capacity of 215 F g(-1). H3PO4-polyvinyl alcohol gel with an optimized component ratio was introduced as both binder and stretchable electrolyte, which contributed to the regularity and stability of the buckled fiber array. The buckled structure and the quasi one-dimensional character of the fibers endow the supercapacitor with 100% stretchability along all directions. In addition, the supercapacitor exhibited good transparency, as well as excellent electrochemical properties and stability after being stretched 5000 times.
Visible-light-driven
CO2 reduction technology offers
a promising solution for the worldwide challenges of climate crisis
and energy shortage. A key issue in photocatalysis is to develop environmentally
benign, low-cost materials ideally with earth-abundant elements with
suitable oxidizing and reducing potentials. Herein, by means of density
functional theory computations and swarm-intelligence structure-searching
method, we predicted the metal-free two-dimensional B4C3 monolayer as a promising green photocatalyst. Extended from
a quasi-planar B4C3 cluster, the newly proposed
boron carbide monolayer has not only novel tetracoordinate carbon
atoms but also strong visible-light absorption, appropriate band edge
alignments, and high carrier mobility, which endow the B4C3 monolayer’s great potential for the photocatalytic
CO2 reduction. The computations of Gibbs free energy also
suggest the energetic favorability in photoreduction of CO2. Remarkably, as the global minimum structure, the predicted B4C3 sheet is highly realizable in the experiment,
as indicated by the impressive in-plane stiffness and weak interaction
between the B4C3 and Si substrate.
The direct growth of single-walled carbon nanotubes (SWCNTs) with narrow chiral distribution remains elusive despite substantial benefits in properties and applications. Nanoparticle catalysts are vital for SWCNT and more generally nanomaterial synthesis, but understanding their effect is limited. Solid catalysts show promise in achieving chirality-controlled growth, but poor size control and synthesis efficiency hampers advancement. Here, we demonstrate the first synthesis of refractory metal nanoparticles (W, Mo, and Re) with near-monodisperse sizes. High concentrations (N = 105 to 107 cm−3) of nanoparticles (diameter 1 to 5 nm) are produced and reduced in a single process, enabling SWCNT synthesis with controlled chiral angles of 19° ± 5°, demonstrating abundance >93%. These results confirm the interface thermodynamics and kinetic growth theory mechanism, which has been extended here to include temporal dependence of fast-growing chiralities. The solid catalysts are further shown effective via floating catalyst growth, offering efficient production possibilities.
We formulate and prove the Lorentzian version of the positive mass theorems with arbitrary negative cosmological constant for asymptotically AdS spacetimes. This work is the continuation of the second author's recent work on the positive mass theorem on asymptotically hyperbolic 3-manifolds.
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