Cumulative damage during fatigue is studied analytically. Extensive reviews are per formed on the published damage models. Three different cumulative damage models are defined using several physical variables such as fatigue modulus and resultant strain. Proposed model I is defined using fatigue modulus, while models II and III are defined using resultant strains. Proposed models are derived as functions of nor malized applied stress level, r, and number of fatigue cycle, n. It is verified that the proposed cumulative damage model III has better agreement with the two stress level fatigue experimental data than other models.
Fatigue behavior of glass fiber reinforced epoxy composite materials has been studied analytically. A new concept called "fatigue modulus," which is defined as a slope of applied stress and resultant strain at a specific cycle is introduced. Fatigue modulus degradation is studied using an assumption that the fatigue modulus degrada tion rate follows a power function of fatigue cycle. Theoretical equation for predicting fatigue life is formulated using the fatigue modulus and its degradation rate. This rela tion is simplified by strain failure criterion for the practical application. It is proved that the final formula predicts the fatigue life of a glass fiber epoxy composite material better than S-N curve or Basquin's relation. An attempt is made to find the relation ship between fatigue modulus and elastic modulus by the geometric relation from stress-strain curve under the cyclic loading.
A square-planar Pt(II) complex with a pyridine-based pincer-type N-heterocyclic carbene ligand, [PtII(C∧N∧C)(Cl)]Cl (C∧N∧C = 2,6-bis(1-butylimidazol-2-ylidenyl)pyridine), was synthesized as a new type of emitter and structurally characterized. The complex shows aquachromic photoluminescence in the solid state upon hydration and dehydration.
A one-step and mass-production synthetic route for a flexible reduced tungsten oxide-carbon composite nanofiber (WO(x)-C-NF) film is demonstrated via an electrospinning technique. The WO(x)-C-NF film exhibits unprecedented high content of metal-oxides (∼ 80 wt%) and good flexibility (the tensile strength of the specimen was 6.13 MPa) without the use of flexible support materials like CNTs or graphene. The WO(x)-C-NF film is directly used as an anode in a lithium ion battery (LIB). Compared with previously reported tungsten oxide electrodes, the WO(x)-C-NF film exhibits high reversible capacity (481 mA h g(-1)total electrode), stable cycle, and improved rate performance, without the use of additive carbon, a polymeric binder and a current collector. Moreover, control electrodes fabricated by conventional processes support the positive effects of both the freestanding electrode and metal-oxide embedded carbon 1-D nanofiber structure.
With increasing amounts of oily water discharged from industrial and domestic sources, purifying oily emulsions using effective and eco-friendly methods is of great significance. Although functional membranes with selective wettabilities have been extensively explored for the efficient purification of oil-inwater emulsions, the development of functional membranes that use green and inexpensive materials, are simple to fabricate, and are easy to scale up remains very challenging. Herein, we report a simple approach that uses biomass to prepare a membrane for the purification of emulsions. A simple top-down approach was used to partially remove lignin and hemicellulose fractions in wood sheets, resulting in a highly porous and flexible wood membrane. The obtained wood membrane shows excellent water-absorbing and underwater anti-oil adhesion properties due to the removal of the hydrophobic lignin. The wood membrane is durable and stable, thereby maintaining its selective wettability in harsh environments. Selective wetting properties along with a porous structure enable the wood membrane to purify surfactant-stabilized oil-in-water emulsions. Such a biomass-derived membrane, which is green, inexpensive, easy to fabricate, and scalable, along with its selective wettability and durability, shows great potential for use as a substitute for existing filter media in diverse industries.
Intra-granular Acicular Ferrite (IAF), as one of the most well-known desirable microstructure of ferrite with a chaotic crystallographic orientation, can not only refine the microstructure and retard the propagation of cleavage crack but also provide excellent combination of strength and toughness in steel. The effect of adding cerium on microstructure and controlling proper cerium-based inclusions in order to improve properties in low-carbon commercial steel (SS400) were investigated. The type of inclusions can be controlled by changing S/O ratio and Ce content. Without Ce modification, MnS is a dominate inclusion. After adding Ce, the stable inclusion phases change from AlCeO3 to Ce2O2S. The optimum amount of cerium, 0.0235 wt.%, lead in proper grain refinement and formation of cerium oxide, oxy-sulfide and sulfide inclusions. Having a high amount of cerium results in increasing the number of inclusions significantly as a result it cannot be effective enough and the inclusions will act like barriers for others. It is found that the inclusions with a size of about 4∼7 μm can serve as heterogeneous nucleation sites for AF formation. Thermodynamic calculations have been applied to predict the inclusion formation in this molten steel as well, which show a good agreement with experimental one.
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