Light-initiated polymerization processes are currently an important tool in various industrial fields. The advancement of technology has resulted in the use of photopolymerization in various biomedical applications, such as the production of 3D hydrogel structures, the encapsulation of cells, and in drug delivery systems. The use of photopolymerization processes requires an appropriate initiating system that, in biomedical applications, must meet additional criteria such as high water solubility, non-toxicity to cells, and compatibility with visible low-power light sources. This article is a literature review on those compounds that act as photoinitiators of photopolymerization processes in biomedical applications. The division of initiators according to the method of photoinitiation was described and the related mechanisms were discussed. Examples from each group of photoinitiators are presented, and their benefits, limitations, and applications are outlined.
Application of new photoinitiator-catalyst systems based on meta-terphenyl derivatives as photosensitisers of iodonium and thianthrenium salts for visible photopolymerization in 3D printing.
Summary of properties and applications of multifunctional of biphenyl derivatives as photosensitisers in various types of photopolymerization processes, including IPN formation, 3D printing of photocurable multiwalled carbon nanotubes (MWCNTs) fluorescent composites.
Light-initiated polymerization processes are currently an important tool in various industrial fields. The advancement of technology has resulted in the use of photopolymerization in various biomedical applications, such as the production of 3D hydrogel structures, the encapsulation of cells, and in drug delivery systems. The use of photopolymerization processes requires an appropriate initiating system which, in biomedical applications, must meet additional criteria: high water solubility, non-toxicity to cells, and compatibility with visible low-power light sources. This article is a literature review on those compounds that act as photoinitiators of photopolymerization processes in biomedical applications. The division of initiators according to the method of photoinitiation was described and the related mechanisms were discussed. Examples from each group of photoinitiators are presented, and their benefits, limitations and applications are outlined.
We present a group of seven new advanced symmetric iodonium
salts
bearing two benzylidene-based chromophores. This is the first example
of the use of a double bond in the structure of a symmetric iodonium
salt. Such an improvement ensures excellent absorbing properties in
the UV-A and visible range, representing a significant advance over
the commonly used diaryliodonium salts. New symmetric iodonium derivatives
effectively photoinitiate cationic polymerization using light-emitting
diodes (LEDs) with no additives. Thus, they can act as one-component
photoinitiators even in visible light, where common diaryliodonium
salts remain inactive. They can be used in advanced applications such
as three-dimensional (3D) VAT printing using an LCD printer. In addition,
it was possible to study in detail substituent effects on the properties
of the new iodonium salts due to the easily modifiable structure of
the benzylidene chromophore. The research described represents a significant
advance in the development of iodonium salts.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.