It led to the hypothesis that axial elongation occurs by production of BM in the retro-equatorial region leading to a decreased RPE density and retinal thinning in that region and a more tube-like than spherical enlargement of the globe, without compromise in the density of the macular RPE cells and in macular retinal thickness. The increased disc-fovea distance in axially myopic eyes is caused by the development and enlargement of parapapillary, BM free, gamma zone while the length of macular BM, and indirectly macular RPE cell density and macular retinal thickness, remain constant. The target tissue for medical modification of emmetropization/myopization may be the RPE, producing and elongating BM in the retro-equatorial region.
Plasmonic shaped AgX:Ag (X = Cl, Br) nanoparticles have been synthesized by a facile and versatile glycerol-mediated solution route. The as-prepared AgX:Ag nanoparticles exhibit regular shapes, i.e., cube-tetrapod-like AgCl:Ag nanoparticles and AgBr:Ag nanoplates. Compared with the pristine AgX, AgX:Ag nanocomposites display stronger absorption in the visible region due to the surface plasmon resonance of silver nanoparticles. The calculation of bandgaps and band positions indicates the as-achieved AgX:Ag nanoparticles can be used as a class of potential photocatalyst for the reduction of CO(2). For example, reduction of CO(2) under visible light irradiation with the assistance of the anisotropic AgX:Ag nanoparticles yields as much as 100 μmol methanol in the products. Furthermore, the AgX:Ag nanoparticles can maintain its structure and activity after 3 runs of reactions. Therefore, the present route opens an avenue to acquire plasmonic photocatalysts for conversion of CO(2) into useful organic compounds.
The exploitation of highly efficient carbon dioxide reduction (CO2RR) electrocatalyst for methane (CH4) electrosynthesis has attracted great attention for the intermittent renewable electricity storage but remains challenging. Here, N‐heterocyclic carbene (NHC)‐ligated copper single atom site (Cu SAS) embedded in metal–organic framework is reported (2Bn‐Cu@UiO‐67), which can achieve an outstanding Faradaic efficiency (FE) of 81 % for the CO2 reduction to CH4 at −1.5 V vs. RHE with a current density of 420 mA cm−2. The CH4 FE of our catalyst remains above 70 % within a wide potential range and achieves an unprecedented turnover frequency (TOF) of 16.3 s−1. The σ donation of NHC enriches the surface electron density of Cu SAS and promotes the preferential adsorption of CHO* intermediates. The porosity of the catalyst facilitates the diffusion of CO2 to 2Bn‐Cu, significantly increasing the availability of each catalytic center.
A polyaniline (PANI)/carbon nitride nanosheets (CNNS) composite hydrogel with 3D hierarchical nanostructure is synthesized via in situ polymerization. The 3D hierarchical structure is robust and stable, making the composite hydrogel separation-free and easy to recycling. It is highly excellent in removing organic pollutant for PANI/CNNS composite hydrogel on account of the cooperation of adsorptive preconcentration and the following photocatalytic oxidation. Pollutants are first adsorbed and concentrated into the 3D hierarchical nanostructure of the composite hydrogel. Then the pollutants are in situ oxidized via photocatalysis. The promoted photocatalytic performance can be mainly ascribed to the outstanding interfacial charge separation and photoelectrochemical performance. A new idea of the construction of 3D hierarchical photocatalysts is presented, which can be applied in the sustainability field.
The present study was conducted to investigate the effects of outdoor access on the growth performance and meat quality of broiler chickens. Thirty-five-day-old female broilers were divided into 3 groups with 6 replicates of 124 birds each: (1) birds reared indoors (control group); (2) birds reared with outdoor access since 36 d of age (35-d group); and (3) birds reared with outdoor access since 71 d of age (70-d group). The results showed that outdoor access had no effect on growth performance, carcass yield, meat yield, muscle protein content, muscle fiber characteristics, or water-holding capacity (P > 0.05). Chickens from the outdoor access groups had a better appearance and degree of evenness. Birds in the outdoor access groups had a significantly lower lung percentage than birds in the control group (P < 0.05), whereas the kidney percentage of the 35-d group was significantly lower than that of the control group (P< 0.05). The meat of chickens in the 35-d group had higher L* values than that of the control group (P < 0.05). Compared with rearing indoors, outdoor access significantly increased the shear force of the breast muscle in both the 35 d and 70-d group (P < 0.05) and decreased the fat content of the thigh muscle in the case of 35-d group (P < 0.05). Birds in the 35-d group also had lower fat content in their thigh muscles than did the birds in the 70-d group (P < 0.05). The thigh muscles of the birds in the 35-d group showed lower levels of MUFA and higher levels of PUFA than those of the control group and 70-d group (P < 0.05). In conclusion, outdoor access had no effect on growth performance and yield traits but could improve the meat quality; birds reared with outdoor access from 36 d of age had better appearance and meat quality than those with outdoor access from 71 d of age.
Schematic illustration of the tailored process from bulk g-C3N4 to two typical tailored morphologies (CNPSs and CNQDs) by treatment of different NH3/H2O2 volume ratios.
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