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2016) Synthesis of nanosized TiO 2 powder by sol gel method at low temperature, Molecular Crystals and Liquid Crystals, 627:1, 170-175, ABSTRACTNanotechnology is all about making products from very small constituents, components or subsystems to gain greatly enhanced material properties and functionality. Nanocrystalline anatase TiO 2 was prepared by a facile sol-gel route at a temperature of 50°C under mild conditions. Titanium tetraisopropoxide (TTIP) was used as a titanium precursor, and 2-propanol was used as a solvent. XRD, TEM, SEM, FT-IR and BET were applied to characterize the crystal phase. The Crystalline size of TiO 2 powder has been obtained with diameter < 30 nm for anatase at 500°C using an acid.

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TiO 2 nanoparticles are prepared via sol-gel method using titanium tetraisopropoxide (TTIP) as a precursor under refluxing and controlled pH. It is found that pure anatase phase is obtained with pH 10. Further characterization studies are carried out on pure nanoparticle anatase phase by XRD, SEM, and transmission electron microscope (TEM). Their electrochemical performances as anode material in lithium-ion batteries are investigated by cyclic voltammetry, galvanostatic cycling, and rate capability measurements. A high discharge capacity of 321 mAh/g (vs. 335 mAh/g theoretical) is achieved at 1C rate. After the first galvanostatic charge/discharge cycle, voltage profiles show plateaus at 1.75 and 1.95 V versus Li at discharge and charge, respectively. High Coulombic efficiency (>99%) is maintained after 300 cycles, which makes anatase TiO 2 nanoparticles prepared by sol-gel method, a very promising material for anode application in lithium rechargeable batteries.