We investigate herein the excited
state dynamics and
symmetry breaking
processes in three benzothiazole-derived two-photon absorbing chromophores
by femtosecond fluorescence and transient absorption (fs-TA) spectroscopies
in solvents of various polarity. The chromophores feature a quasi-quadrupolar D-π-A-π-D architecture
comprised of an
electron-withdrawing benzothiazole core and lateral triphenylamine
donors (Qbtz-H), while the acceptor strength of the central
unit is enforced by attached cyano groups (Qbtz-CN) and
the electron-donating strength of the arylamine moieties by introduction
of peripheral methoxy groups (Qbtz′-CN). Steady
state spectroscopy reveals positive solvatochromism, which is mostly
pronounced for Qbtz′-CN. Femtosecond spectroscopy
of Qbtz-H reveals the coexistence of the Franck–Condon
(FC) state and states populated after symmetry breaking (SB) in low-polarity
solvents such as toluene and tetrahydrofuran, while the SB state becomes
favorable in polar acetonitrile. For the other two molecules possessing
a stronger electron-accepting unit and thus more polar excited state,
SB takes place even in low-polarity solvents, as shown by fs-TA spectroscopy.
Global fitting of the fs-TA spectra together with investigation of
the evolution associated spectra (EAS) reveals the existence of an
initial FC state in Qbtz-H, in all studied solvents,
which relaxes toward Intermediate Charge Transfer (I-CT) and SB states.
On the other hand, for Qbtz-CN and Qbtz′-CN in more polar solvents, the FC state undergoes ultrafast relaxation
toward symmetry-broken charge transfer (SB-CT) states which in turn
show very fast recombination to the ground state. Our measurements
confirm that the extent of symmetry breaking is larger for D-π-A-π-D
systems with the stronger acceptor core and increases further by increasing
electron-donating strength of triarylamine moieties, giving rise to
symmetry breaking in these nonionic quadrupolar molecules with ethynylene
(triple bond) π-spacers also in less polar solvents.
Here, we use a simple
and effective method to accomplish energy level alignment and thus
electron injection barrier control in organic light emitting diodes
(OLEDs) with a conventional architecture based on a green emissive
copolymer. In particular, a series of functionalized zinc porphyrin
compounds bearing π-delocalized triazine electron withdrawing
spacers for efficient intramolecular electron transfer and different
terminal groups such as glycine moieties in their peripheral substitutes
are employed as thin interlayers at the emissive layer/Al (cathode)
interface to realize efficient electron injection/transport. The effects
of spatial (i.e., assembly) configuration, molecular dipole moment
and type of peripheral group termination on the optical properties
and energy level tuning are investigated by steady-state and time-resolved
photoluminescence spectroscopy in F8BT/porphyrin films, by photovoltage
measurements in OLED devices and by surface work function measurements
in Al electrodes modified with the functionalized zinc porphyrins.
The performance of OLEDs is significantly improved upon using the
functionalized porphyrin interlayers with the recorded luminance of
the devices to reach values 1 order of magnitude higher than that
of the reference diode without any electron injection/transport interlayer.
In the quest to decipher the chain of life from molecules to cells, the biological and biophysical questions being asked increasingly demand techniques that are capable of identifying specific biomolecules in their native environment, and can measure biomolecular interactions quantitatively, at the smallest possible scale in space and time, without perturbing the system under observation. The interaction of light with biomolecules offers a wealth of phenomena and tools that can be exploited to drive this progress. This Roadmap is written collectively by prominent researchers and encompasses selected aspects of bio-nano-photonics, spanning from
The effect of the local photo-triggered heat release on the motion of organic NP, a process that is itself thermal, under low intensity irradiation is largely unexplored. Here, we develop...
One-dimensional (1D) linear nanostructures comprising sp-hybridized carbon atoms, as derivatives of the prototypical allotrope known as carbyne, are predicted to possess outstanding mechanical, thermal, and electronic properties. Despite recent advances in their synthesis, their chemical and physical properties are still poorly understood. Here, we investigate the photophysics of a prototypical polyyne (i.e., 1D chain with alternating single and triple carbon bonds) as the simplest model of finite carbon wire and as a prototype of spcarbon-based chains. We perform transient absorption experiments with high temporal resolution (<30 fs) on monodispersed hydrogen-capped hexayne H�(C�C) 6 �H synthesized by laser ablation in liquid. With the support of computational studies based on ground state density functional theory (DFT) and excited state time-dependent (TD)-DFT calculations, we provide a comprehensive description of the excited state relaxation processes at early times following photoexcitation. We show that the internal conversion from a bright highenergy singlet excited state to a low-lying singlet dark state is ultrafast and takes place with a 200 fs time constant, followed by thermalization on the picosecond time scale and decay of the low-energy singlet state with hundreds of picoseconds time constant. We also show that the time scale of these processes does not depend on the end groups capping the sp-carbon chain. The understanding of the primary photoinduced events in polyynes is of key importance both for fundamental knowledge and for potential optoelectronic and light-harvesting applications of low-dimensional nanostructured carbon-based materials.
Benzothiazole is among prominent electron-withdrawing heteroarene moieties used in a variety of π-conjugated molecules. Its relative orientation with respect to the principal dipole vector(s) of chromophores derived thereof is crucial, affecting photophysical and nonlinear optical properties. Here we compare the photophysics and ultrafast dynamics of dipolar and octupolar molecules comprising a triphenylamine electron-donating core, ethynylene π-conjugated linker(s) and benzothiazole acceptor(s) having the matched or mismatched orientation (with respect to the direction of intramolecular charge transfer), while a carbaldehyde group is attached as an auxiliary acceptor.Among chromophores without the auxiliary acceptor, stronger fluorescence solvatochromism and faster excited state dynamics are exhibited for the derivatives with the mismatched geometry. On the contrary, introduction of the auxiliary acceptor to the benzothiazole unit enhances the intramolecular charge transfer ICT (featuring ultrafast dynamics of the excited state) for the matched geometry. The data confirm the crucial role of the relative orientation of asymmetric heteroaromatic unit (regioisomeric effect) in dipolar as well as in multipolar molecules in tuning linear and nonlinear optical properties as well as excited state dynamics.
Multidimensional spectroscopies reveal a two-step process in a biomimetic supracomplex for oxygen evolution. A sub-ps charge-separation within the light-sensitizer moiety is followed by hole transfer from the catalyst counterpart, forming productive charges.
Multidimensional spectroscopies unveil the presence of vibronic coupling within the Q-states in a free-base porphyrin. High-frequency coupling and tuning modes drive the ultrafast internal conversion and track the excited state structural evolution.
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