A novel strategy to functionalize transparent flexible plastic films with an optical ion-sensing layer using an inkjet-printing technology is described. The hydrophobic sensing chemicals that include a sodium ionophore, a lipophilic proton chromoionophore, and a lipophilic ion-exchanger are co-deposited onto substrates such as transparent polyester film sheets in the absence of any plasticizer and/or hydrophobic polymer matrix. The inkjet-printing process enables the formation of optode films with nanoscale thickness/roughness that readily facilitate interfacing with aqueous samples. Using a smartphone detector, the colorimetric response of the optodes is shown to reach 95% of equilibrium values within 100 s in response to different concentrations of sodium ions, which is more rapid than traditional ion-selective optodes based on plasticized PVC films as the sensing layer. The new optodes also exhibit high selectivity to Na+ over interfering ions including K+, Ca2+, and Mg2+. Chemical leaching experiments show that the highly hydrophobic optode components remain in place on the plastic substrate surface. Hence, excellent sensor stability and fully reversible optical responses are obtained, which is essential for potential continuous monitoring applications. Further testing of the sensors with undiluted human sweat samples is shown to yield accurate values for sodium concentrations. Therefore, the use of plasticizer-free ion-selective optode nanolayers that enable highly selective ion sensing on a clear plastic support is likely to expand the range of available chemical sensors suited for preparing wearable real-time sweat analysis devices.
O uso de fertilizantes de liberação controlada constitui-se em uma das modernas técnicas na produção de mudas. Porém existem poucos relatos de seus efeitos sobre o crescimento inicial de espécies florestais nativas em área de domínio ciliar. O estudo objetivou comparar os efeitos de diferentes fertilizantes de liberação lenta (FLL) com uma formulação convencional no crescimento a campo de mudas de Anadenanthera colubrina e Tabebuia avellanedae. As mudas foram plantadas com 55 g por cova de Basacote 3M, Basacote 6M, Basacote 9M, formulação 16-8-12, e uma testemunha (sem fertilização). As mensurações não destrutivas incluíam os incrementos em altura, diâmetro do coleto e número de folhas aos 90, 180, 270 e 360 dias após o plantio, e avaliações destrutivas da massa seca aérea e radicular em mudas escavadas aos 180 e 360 dias após o plantio. Os resultados revelaram maior incremento para o diâmetro do coleto e o número de folhas em A. colubrina com FLL, enquanto que mudas de T. avellanedae expressaram maiores respostas em incrementos de altura. As biomassas secas da raiz e aérea não foram influenciadas pela adição de fertilizantes na cova, apresentando apenas diferenças entre as espécies.Palavras-chave: Crescimento inicial; Anadenanthera colubrina; Tabebuia avellanedae; fertilizante de liberação lenta. AbstractEffects of fertilizers applied to ipe roxo and angico during their seedlings planting. Slow release fertilizer (SRF) is a modern tool for seedling production. However, there are few reports on the effects of its application on initial growth of native forest species planted on repairing areas. The aim of this experiment was to compare the effects of SRF and a conventional fertilizer on initial growth of fields planted with Anadenanthera colubrine and Tabebuia avellanedae seedlings. Treatments included 55 g per planting hole of Basacote 3M, Basacote 6M, Basacote 9M, conventional fertilizer NPK (16-8-12) and a control (no fertilizer). Non destructive measurements included increments of root collar, length, and number of leaves at 90, 180, 270 and 360 days after planting date. Destructive measurements included dried biomass of above and bellow ground tissues, root length, and leaf area of three seedling randomly selected from each treatment. The results showed higher increments in root collar diameter and number of leaves for A. colubrine with SRF while T. avellanedae seedlings showed higher increments in plant height. Differences in relation to above and below ground dry masses were detected only between species at 180 and 360 days after planting date.Keywords: Initial growth; Anadenanthera colubrina; Tabebuia avellanedae; slow release fertilizer.
A layer of a solvatochromic dye, an ionophore, and an ion-exchanger deposited on a Nylon membrane enables highly selective colorimetric and fluorometric ion sensing.
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