International audienceThe Ili-Balkhash Basin in southeastern Kazakhstan is located at the junction of the actively deforming mountain ranges of western Junggar and the Tien Shan, and is therefore part of the southwestern Central Asian Orogenic Belt. The basement of the Ili-Balkhash area consists of an assemblage of mainly Precambrian microcontinental fragments, magmatic arcs and accretionary complexes. Eight magmatic basement samples (granitoids and tuffs) from the Ili-Balkhash area were dated with zircon U-Pb LA-ICP-MS and yield Carboniferous to late Permian (~ 350-260 Ma) crystallization ages. These ages are interpreted as reflecting the transition from subduction to (post-) collisional magmatism, related to the closure of the Junggar-Balkhash Ocean during the Carboniferous – early Permian and hence, to the final late Paleozoic accretion history of the ancestral Central Asian Orogenic Belt. Apatite fission track (AFT) dating of 14 basement samples (gneiss, granitoids and volcanic tuffs) mainly provides Cretaceous cooling ages. Thermal history modeling based on the AFT data reveals that several intracontinental tectonic reactivation episodes affected the studied basement during the late Mesozoic and Cenozoic. Late Mesozoic reactivation and associated basement exhumation is interpreted as distant effects of the Cimmerian collisions at the southern Eurasian margin and possibly of the Mongol-Okhotsk Orogeny in SE Siberia during the Jurassic – Cretaceous. Following tectonic stability during the Palaeogene, inherited basement structures were reactivated during the Neogene (constrained by Miocene AFT ages of ~ 17–10 Ma). This late Cenozoic reactivation is interpreted as the far-field response of the India-Eurasia collision and reflects the onset of modern mountain building and denudation in southeast Kazakhstan, which seems to be at least partially controlled by the inherited basement architecture
On the basis of stratigraphical and geological data, paleogeographical and palinspastic reconstructions of the Kazakhstan Paleozoides were done; their multistage geodynamic evolution was considered; their tectonic zoning was proposed. The main stages are described: the initiation of the Cambrian and Ordovician island arcs; the development of the Kazakhstan accretionary–collisional composite continent in the Late Ordovician as a result of continental subduction and the amalgamation of Gondwana blocks with the island arcs (a long granitoid collisional belt also formed in this period); the development of the Devonian and Carboniferous–Permian active margins of the composite continent and its tectonic destruction in the Late Paleozoic. In the Late Ordovician, compensated terrigenous and volcanosedimentary complexes formed within Kazakhstania and developed in the Silurian. The Sakmarian, Tagil, Eastern Urals, and Stepnyak volcanic arcs formed at the boundaries with the Ural, Turkestan, and Junggar–Balkhash Oceans. In the late Silurian, Kazakhstania collided with the island arcs of the Turkestan and Ob’–Zaisan Oceans, with the formation of molasse and granite belts in the northern Tien Shan and Chingiz. This was followed by the development of the Devonian and Carboniferous–Permian active margins of the composite continent and the inland formation of the Early Devonian rift-related volcanosedimentary rocks, Middle–Late Devonian volcanic molasse, Late Devonian–Early Carboniferous rift-related volcanosedimentary rocks, terrigenous–carbonate shelf sediments, and carbonaceous lake–bog sediments, and the Middle–Late Carboniferous clastic rocks of closed basins. In the Permian, plume magmatism took place on the southern margin of the Kazakhstan composite continent. It was simultaneous with the formation of red-colored molasse and the tectonic destruction of the Kazakhstan Paleozoides as a result of a collision between the East European and Kazakhstan–Baikal continents.
Nickel weathering ores are used to produce metallic nickel, stainless steels, and nickel sulfate, the main component of batteries. The global production of nickel from weathering ores is increasing and has surpassed production from sulfide magmatic deposits. The efficiency of the mining and processing of nickel ores from weathering rocks is determined by their mineralogical composition. The weathering crust profile of the Kempirsay ultramafite massif is divided into three zones—leached (kerolitized) serpentinites, nontronites, and final hydrolysis minerals (later referred to as “ochers”). The kerolitized zone consists of a mixture of Ni-bearing talc and saponites (later referred to as “kerolite”). During the geological mapping of the Donskoye, Buranovskoye, and Shelektinskoye deposits, the products of ultramafite hypergenic transformation into disintegrated and leached serpentinites, kerolites, nontronites, and ochers were selected and studied. For this purpose, 44 rock samples were studied via X-ray diffractometric and thermal analyses, supplemented with data from chemical, microscopic, and granulometric determinations. Based on the obtained numerical parameters of the crystalline structure of the weathering products, the thermochemical values were obtained. The hypergenic transformation of the initial minerals and their subsequent transformation were traced. The trace element distribution along the profile of the serpentinite weathering ores is related to the initial material composition of the ultramafites. The accumulation of nickel in industrial concentrations is associated with the nontronite–kerolite zone. X-ray diffractometric analysis can be used as a fast and reliable method for controlling the nickel content of ores and monitoring their mineralogical composition.
Various genetic and morphological types of voids in carbonate reservoirs make it difficult to diagnose them, which can be seen in the determination of reservoir properties in the northern marginal shear zone of the Caspian Syneclise. A macro- and microscopic study of rocks was carried out by staining carbonates in thin sections with alizarin (determination of the mineral composition, structure, texture, void and fracture spaces, rock genesis). Instrumental methods (X-ray, DTA - differential thermal analysis, TGA - thermo-gravimetric analysis, and probe microanalysis) established the composition of rocks, the nature of their diagenetic transformations, and the formation of void space. The elemental and oxide composition of a number of samples was carried out using the X-ray probe microanalysis method, and mineral formations with intermediate thermochemical properties were found. The results of X-ray, DTA, and TGA measurements and the data of probe microanalysis made it possible to reveal thermally inert formations of oxides of calcium, magnesium, silicon, iron, and other compounds in the composition of carbonates. A relatively low-cost express method was used to determine the material composition and the nature of epigenetic changes and to obtain data on the void space as a result of the development of tectonic fracturing and diagenetic processes of leaching and secondary mineral formation in bedded carbonate reservoirs.
The article deals with the issues of tectonic zoning of the Paleozoic and Mesozoic-Cenozoic structures of Kazakhstan. The principles of tectonic zoning are outlined, on the basis of which the zoning and indexation of tectonic units of the territory of Kazakhstan was carried out. For this, various data of complex geological and geophysical analysis of Paleozoids were used, including tectonic, structural, stratigraphic, lithological-paleogeographic, petrographic, geodynamic and other studies. A geological and tectonic scheme (model) is proposed that reflects the main tectonic units that make up the structural framework of the Paleozoids of Kazakhstan, consisting of a crystalline basement on which the formation of sedimentary oil and gas basins took place. The main tectonic units of the earth's crust of the territory under consideration are identified and characterized, and the mosaic-block structure of the complexes is shown. The characteristic of the complex multi-stage evolution of the paleozoids of Kazakhstan and its oil and gas regions is given.
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