Electrical resistivity, thermal expansion, and temperature-dependent x-ray diffraction measurements on compounds give mutually consistent evidence for structural phase transitions at 740 K, 550 K, 600 K, and 450 K respectively for R = Y, Sm, Gd, Tb; 0 < x < 0.05. Arguments are given as to why most of the rare-earth - nickel compounds with the 1:2 ratio do not crystallize in the simple cubic Laves phase (C15 type) but show a superstructure of the cubic Laves phase at room temperature and at ambient pressure. This superstructure with the space group and a doubled cell parameter is characterized by ordered vacancies on the R sites. It is shown that the observed structural instabilities result in transitions to the cubic Laves phase (space group ), however with disordered vacancies at high temperatures. High-pressure x-ray powder diffraction experiments show that the phase transition in shifts down to room temperature for a pressure of 27 GPa.
Bi2Te3 and CoSb3 based nanomaterials were synthesized and their thermoelectric, structural, and vibrational properties analyzed to assess and reduce ZT‐limiting mechanisms. The same preparation and/or characterization methods were applied in the different materials systems. Single‐crystalline, ternary p‐type Bi15Sb29Te56, and n‐type Bi38Te55Se7 nanowires with power factors comparable to nanostructured bulk materials were prepared by potential‐pulsed electrochemical deposition in a nanostructured Al2O3 matrix. p‐type Sb2Te3, n‐type Bi2Te3, and n‐type CoSb3 thin films were grown at room temperature using molecular beam epitaxy and were subsequently annealed at elevated temperatures. This yielded polycrystalline, single phase thin films with optimized charge carrier densities. In CoSb3 thin films the speed of sound could be reduced by filling the cage structure with Yb and alloying with Fe yielded p‐type material. Bi2(Te0.91Se0.09)3/SiC and (Bi0.26Sb0.74)2Te3/SiC nanocomposites with low thermal conductivities and ZT values larger than 1 were prepared by spark plasma sintering. Nanostructure, texture, chemical composition, as well as electronic and phononic excitations were investigated by X‐ray diffraction, nuclear resonance scattering, inelastic neutron scattering, Mössbauer spectroscopy, and transmission electron microscopy. For Bi2Te3 materials, ab‐initio calculations together with equilibrium and non‐equilibrium molecular dynamics simulations for point defects yielded their formation energies and their effect on lattice thermal conductivity, respectively.
Current advances in thermoelectric Bi2Te3 and CoSb3 based nanomaterials are summarized. Advanced synthesis and characterization methods and theoretical modeling were combined to assess and reduce ZT‐limiting mechanisms in these materials.
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